一种环境水样中五种新烟碱类杀虫剂的检测方法

By using conjugated microporous polymer materials as solid-phase extraction adsorbents combined with high-performance liquid chromatography, the problem of efficient detection of neonicotinoid insecticides in environmental water samples was solved, achieving efficient, simple, and low-cost detection results.

CN117907493BActive Publication Date: 2026-07-17BIOTECH CENT OF SHANDONG ACAD OF SCI

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
BIOTECH CENT OF SHANDONG ACAD OF SCI
Filing Date
2023-12-01
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing detection methods are difficult to efficiently and cost-effectively separate and detect neonicotinoid pesticides from environmental water samples, and traditional adsorbents have small adsorption capacity and poor selectivity.

Method used

Conjugated microporous polymer materials were used as solid-phase extraction adsorbents, combined with high-performance liquid chromatography, and CMP materials were prepared via Sonogashira coupling reaction for the extraction, enrichment, and detection of neonicotinoid insecticides in environmental water samples.

Benefits of technology

It achieves efficient, simple, and low-cost detection of neonicotinoid insecticides, improves the specific surface area and selectivity of the adsorbent, simplifies the sample pretreatment process, reduces analysis time and cost, and provides good accuracy and reproducibility of the detection results.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明提供了一种环境水样中五种新烟碱类杀虫剂的检测方法。本发明的方法包括步骤:以1,3,5‑三乙炔基苯、1,4‑二溴苯为原料制备共轭微孔聚合物材料吸附剂;将装有共轭微孔聚合物材料吸附剂的固相萃取小柱依次用乙腈和蒸馏水活化;然后将水样通过固相萃取小柱,进行上样;将上样完成的固相萃取小柱干燥后,用乙腈进行洗脱,收集洗脱液;将洗脱液用氮气吹干后,用色谱纯乙腈溶解,经超声处理、过滤后,使用HPCL检测新烟碱类杀虫剂的浓度。本发明的检测方法操作简便、实用性强,大大节约了分析时间和成本,平均回收率为73.7‑112.0%,相对标准偏差为0.6‑9.4%,萃取效果好,分析结果准确,重现性好。
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