一种六氟磷酸锂的制备方法

By controlling the packing density and reaction conditions of lithium hexafluorophosphate and employing the contact reaction of hydrogen fluoride and phosphorus pentafluoride gas, the problem of residual impurities in lithium hexafluorophosphate was solved, achieving an efficient and safe preparation process and improving the purity and yield of lithium hexafluorophosphate.

CN117917380BActive Publication Date: 2026-07-17SHENZHEN CAPCHEM TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHENZHEN CAPCHEM TECH CO LTD
Filing Date
2022-10-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing methods for preparing lithium hexafluorophosphate suffer from problems such as high levels of residual impurities and operational difficulties. In particular, lithium fluoride and hydroxides are difficult to remove completely, and high-pressure operation poses safety hazards.

Method used

Hydrogen fluoride was used as a solvent, lithium fluoride was added and phosphorus pentafluoride gas was introduced. The bulk density of lithium hexafluoride phosphate was controlled to be 1.5-3.8 g/cm3. After cooling and crystallization, phosphorus pentafluoride gas was introduced to carry out the reaction. The reaction was carried out in multiple contacts and heated and purged under negative pressure to remove unreacted phosphorus pentafluoride gas. The reaction time and temperature were controlled.

Benefits of technology

It effectively reduces the impurity content in lithium hexafluorophosphate, improves yield and purity, simplifies the operation process, avoids high-pressure conditions, and improves production efficiency and safety.

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Abstract

为克服现有六氟磷酸锂的精制方法存在杂质残留量高和操作难度大的问题,本发明提供了一种六氟磷酸锂的制备方法,包括以下操作:以氟化氢作为溶剂,加入氟化锂分散,再通入五氟化磷气体,反应得到六氟磷酸锂浆料;将六氟磷酸锂浆料进行降温结晶,收集结晶的固态六氟磷酸锂并去除液体,控制六氟磷酸锂的堆积密度为1.5~3.8g / cm3;往六氟磷酸锂中通入五氟化磷气体进行反应,反应后脱除未反应的五氟化磷气体,得到六氟磷酸锂成品。本发明提供的六氟磷酸锂的制备方法提高了六氟磷酸锂中氟化锂的转化效率,提高六氟磷酸锂的收率和纯度,且操作难度较低。
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