一种超疏水强酸磁性催化剂及其制备方法和应用

By grafting perfluorosulfonic acid onto Fe3O4@SiO2 microspheres, a superhydrophobic strong acid magnetic catalyst was prepared, solving the problems of acid strength and high temperature resistance of catalysts in the preparation of high-density biomass fuels. This resulted in highly efficient catalytic performance and easy separation, making it suitable for the synthesis of biomass fuel precursors.

CN117943003BActive Publication Date: 2026-07-17NORTHWESTERN POLYTECHNICAL UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
NORTHWESTERN POLYTECHNICAL UNIV
Filing Date
2024-01-29
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing biomass high-density fuel production processes, hydrophobic catalysts have insufficient acid strength and high-temperature resistance, and catalyst separation and recovery are difficult, affecting reaction conversion rate and selectivity.

Method used

Using Fe3O4@SiO2 microspheres as a support, a superhydrophobic strong acid magnetic catalyst was prepared by grafting with perfluorosulfonic acid. Combined with hydrothermal reaction, a mesoporous structure was formed, achieving superhydrophobicity, oleophilicity, and high temperature resistance of the catalyst.

Benefits of technology

The catalyst exhibits high activity, selectivity, and good cycle stability in the synthesis reaction of biomass high-density fuel precursors. It is easy to separate magnetically and is suitable for Aldol condensation and alkylation reactions, with high yield and good industrial application potential.

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Abstract

本发明公开了一种超疏水强酸磁性催化剂及其制备方法和应用,属于固体催化剂及催化技术领域。该磁性催化剂的制备方法包括以下步骤:将Fe3O4、表面活性剂、有机硅源、第一有机溶剂、含氮有机物和水混合发生水热反应,得到有序介孔Fe3O4@SiO2前驱体;将第二有机溶剂和无机盐混合后,加入有序介孔Fe3O4@SiO2前驱体,发生水热反应,得到介孔Fe3O4@SiO2微球;在第三有机溶剂中,保护气体氛围下,介孔Fe3O4@SiO2微球接枝全氟磺酸得到磁性催化剂。该磁性催化剂不仅具有介孔型和超强酸性,而且具有超疏水性和亲油性,磁分离且能承受215℃的高温。
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