一种饲料级磷酸钙盐的制备方法

By first desulfurizing, removing heavy metals, and then defluorinating in wet-process phosphoric acid, metal impurities are selectively removed, solving the problems of white fertilizer production and phosphorus resource waste in traditional processes, and realizing the preparation of high-quality feed-grade calcium phosphate and resource recycling.

CN117945375BActive Publication Date: 2026-07-17WENGFU (GRP) CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
WENGFU (GRP) CO LTD
Filing Date
2024-02-02
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional feed-grade calcium phosphate production processes are difficult to produce high-quality products, resulting in white fertilizer and defluorination residue, which leads to waste of phosphorus resources and decline in product quality, and metal ions are not effectively removed.

Method used

By first desulfurizing and de-gravity-removing the wet-process phosphoric acid to selectively remove metallic impurities, and then adding a defluorinating agent to form calcium fluoride precipitate, which is then washed, filtered, and reacted with calcium oxide or calcium carbonate to prepare feed-grade calcium phosphate, thus achieving resource recycling.

Benefits of technology

It improves phosphorus yield and defluorination effect, produces feed-grade calcium phosphate with fewer impurities, higher quality, no white fertilizer production, high water-soluble phosphorus content, improved economic benefits, and realizes the resource utilization of metal impurities.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明涉及磷化工技术领域,具体公开了一种饲料级磷酸钙盐的制备方法,包括以下步骤:S1、向脱硫脱重后的湿法磷酸中加入沉淀剂和 / 或S3中的气相物质,反应后过滤得到滤渣1和滤液1;S2、向所述滤液1中加入脱氟剂反应,过滤后得到滤渣2和滤液2;S3、将所述滤渣1和滤渣2混合后洗涤过滤,得到滤渣3和滤液3;所述滤渣3与硫酸反应得到气相和固渣,所述气相作为沉淀剂回到S1反应;所述滤液3和滤液2混合后与氧化钙或碳酸钙反应制备得到饲料级磷酸钙盐。本发明所述的制备方法提高了磷收率和脱氟效果,工艺简单,实现资源循环利用,制备得到的饲料级磷酸钙盐杂质少,品质高,无白肥产生,水溶磷占比高。
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