一种磷光主体材料及其制备方法和应用

By employing phenyl-substituted dibenzofuran groups and carbazole as the parent core phosphorescent host material in phosphorescent organic electroluminescent devices, and combining six-membered nitrogen heterocycles and bridging groups, the problems of thermal stability and carrier mobility of the host material were solved, achieving device performance with low driving voltage, high efficiency and long lifetime.

CN117946087BActive Publication Date: 2026-07-17JILIN OPTICAL & ELECTRONICS MATERIALS CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
JILIN OPTICAL & ELECTRONICS MATERIALS CO LTD
Filing Date
2024-02-04
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing phosphorescent organic electroluminescent devices, it is difficult to simultaneously satisfy the requirements of high triplet energy level, good carrier mobility, thermal stability and film formation stability in the selection of host materials, resulting in high driving voltage, low luminous efficiency and short device lifetime.

Method used

Phosphorescent host materials were synthesized by using phenyl-substituted dibenzofuran groups and carbazole as the parent core, introducing a six-membered nitrogen heterocycle, and then performing a Suzuki coupling reaction to enhance electron-hole recombination and improve carrier mobility. Furthermore, the molecular structure was optimized by bridging groups to enhance thermal stability and film-forming properties.

Benefits of technology

Lowering the driving voltage of the device improves luminous efficiency, extends device lifespan, enhances the conductivity and thermal stability of the material, and improves the overall performance of the device.

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Abstract

本发明公开了一种磷光主体材料及其制备方法和应用,属于有机光电材料技术领域。本发明提供了一种可用作为发光层中的绿色磷光主体材料的化合物,以苯基取代的二苯并呋喃基团和咔唑为母核,通过在母核中进一步引入具有强吸电子特性的六元氮杂环,有利于电子的传输,增强电子和空穴的复合,芳基桥联六元氮杂环来进一步提升其中电子的迁移速率;另外,将本发明制备的磷光主体材料应用在有机电致发光器件中作为发光层主体材料,具有良好的热稳定性和成膜性,能降低其器件的驱动电压、提高发光效率,同时延长器件的使用寿命。
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