含高价铜Cu（Ⅲ）钙钛矿型复合金属氧化物及其制备方法和应用
By preparing the high-valent copper Cu(III) perovskite-type composite metal oxide LaMn1-XCuXO3, the problems of instability of high-valent copper materials and the difficulty in degradation of organophosphonates were solved, achieving efficient and environmentally friendly oxidative degradation, which is suitable for industrial applications.
Patent Information
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- WUHAN UNIV OF TECH
- Filing Date
- 2024-01-22
- Publication Date
- 2026-07-17
AI Technical Summary
Existing technologies make it difficult to synthesize stable high-valence copper materials, and existing oxidants suffer from low efficiency, high cost, and significant pollution when treating organophosphonates such as aminotrimethylenephosphonic acid (NTMP).
LaMn1-XCuXO3, a perovskite-type composite metal oxide containing high-valence copper Cu(III), was prepared by all-solid-phase reaction. It was then prepared by low-temperature calcination in air to form a stable perovskite-type crystal structure. Combined with ball milling activation process, it achieved efficient oxidative degradation of organophosphorus compounds.
The prepared high-valence copper Cu(III) perovskite-type composite metal oxide exhibits excellent oxidative degradation effects on organophosphorus compounds, with an oxidation rate of over 60% for NTMP and a removal rate of 88%. The process is simple, environmentally friendly, and suitable for industrial production.
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Figure CN118005080B_ABST