一种从锂云母提锂母液中分离铯铷的萃取体系及方法

By using a composite extraction system in lithium extraction mother liquor from lepidolite, which includes t-BAMBP and TiOA combined with diluents 260# solvent oil and D80 solvent oil, the problem of low cesium-rubidium separation coefficient is solved, achieving efficient and low-cost cesium-rubidium separation, suitable for industrial applications of low-grade resources.

CN118006899BActive Publication Date: 2026-07-17BEIJING UNIV OF TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
BEIJING UNIV OF TECH
Filing Date
2024-02-18
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing technologies, the separation coefficients of Cs+ and Rb+ are low, making the separation of cesium and rubidium resources difficult and costly, which limits their application scope. Furthermore, traditional extractants are not effective in separating low-grade resources.

Method used

A composite extraction system, consisting of 4-tert-butyl-2-(α-methylbenzyl)phenol (t-BAMBP) and triisooctylamine (TiOA) combined with binary diluents 260# solvent oil and D80 solvent oil, was used to separate cesium and rubidium from lithium mica mother liquor. The extraction process was optimized by adjusting the concentration and volume ratio.

Benefits of technology

It significantly improves the separation coefficient of cesium and rubidium, reduces production costs, achieves highly selective extraction and separation of cesium and rubidium, is suitable for low alkalinity and low concentration conditions, reduces waste alkali pollution, and is suitable for industrial applications.

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Abstract

本发明涉及稀有碱金属元素分离领域,具体涉及一种从锂云母提锂母液中分离铯铷的萃取体系及方法。复合萃取体系包括:4‑叔丁基‑2(α‑甲基苄基)酚、三异辛胺,以及稀释剂;所述稀释剂选自260#溶剂油、环己烷、D80溶剂油、二甲苯、石油醚中的至少两种。本发明研究发现,在4‑叔丁基‑2(α‑甲基苄基)酚和三异辛胺的共同作用下,所制备的复合萃取体系可以在萃取段有效提高铯铷的分离系数,有利于对低品位铯铷资源分离提取。
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