一种多重修饰ZIF-8微孔炭电吸附剂的制备方法及其应用

By preparing ZIF-8 microporous carbon electroadsorbents with multiple modifications, and by modifying ZIF-8-derived microporous carbon with carboxyl and quaternary ammonium groups, the problems of limited adsorption capacity and unstable binding of traditional carbon-based materials were solved, and efficient and stable selective removal of nitrates was achieved.

CN118022681BActive Publication Date: 2026-07-17NANJING NORMAL UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
NANJING NORMAL UNIVERSITY
Filing Date
2024-03-07
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional carbon-based materials have limited adsorption capacity and unstable binding between functional groups and materials, making them unable to effectively remove nitrates. Existing electroadsorption treatments are energy-intensive and lack specific adsorption effects.

Method used

A method for preparing ZIF-8 microporous carbon electroadsorbent with multiple modifications was adopted. By modifying ZIF-8-derived microporous carbon with carboxyl and quaternary ammonium groups, its adsorption performance for nitrates was enhanced. The covalent bond between carboxyl and quaternary ammonium groups was used to improve stability and electrostatic adsorption.

Benefits of technology

It improves the adsorption capacity and selective removal effect of nitrate, has strong anti-interference ability, high adsorbent stability and recycling rate, and achieves selective removal of nitrate in complex water bodies.

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Abstract

本发明公开了一种多重修饰ZIF‑8微孔炭电吸附剂的制备方法及其应用,将制备的ZIF‑8衍生微孔炭先羧基化修饰后用季铵基修饰,将多重修饰ZIF‑8微孔炭电吸附剂制成电极,用于除去废水中的硝酸盐。本发明采用多种功能基团改性吸附剂表面,增加了吸附剂表面活性,季铵基提高了吸附剂与离子间的静电吸附作用,提高对硝酸盐的去除效果,硝酸盐的吸附容量高达0.578mmol / g;先用羧基修饰ZIF‑8衍生微孔炭,再将季铵基共价接枝在其表面,季铵基通过共价键结合在ZIF‑8衍生微孔炭表面,提高了吸附剂的稳定性和循环使用率;可以选择性的吸附多溶质硝酸盐体系,能够实现复杂水体中硝酸盐的选择性去除,抗干扰能力强。
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