一种铈铁固溶体催化剂的制备方法及应用
By preparing cerium-iron solid solution catalysts through eutectic solvent regulation, the problems of low conversion rate and poor selectivity in the cyclohexane oxidation process were solved, realizing the preparation and use of efficient and environmentally friendly catalysts, and improving the conversion rate of cyclohexane and the selectivity of KA oil.
Patent Information
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- INSTITUTE OF PROCESS ENGINEERING CHINESE ACADEMY OF SCIENCES
- Filing Date
- 2022-11-03
- Publication Date
- 2026-07-17
AI Technical Summary
Existing cyclohexane oxidation processes suffer from low conversion rates, poor selectivity, low energy efficiency, and generate a large amount of byproducts and waste. Furthermore, traditional heterogeneous catalysts are costly and have poor recyclability, making it difficult to meet the requirements of green chemistry.
A cerium-iron solid solution catalyst was prepared using a eutectic solvent-assisted method. The catalyst formation process was controlled by forming a eutectic solvent with choline chloride and an organic polybasic acid. A Prussian blue analogue was prepared and calcined to obtain the cerium-iron solid solution catalyst.
It improves the conversion rate of cyclohexane and the selectivity of KA oil, reduces the preparation cost, meets the requirements of green chemistry, and has good catalyst recycling performance.
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Figure CN118022750B_ABST