一种自漂浮Znln2S4 / CeO2 / 碳海绵光催化材料的制备方法及应用

By preparing a self-floating Znln2S4/CeO2/carbon sponge photocatalytic material, the problem of hexavalent uranium reduction and enrichment in the existing technology was solved, achieving a highly efficient uranium extraction effect from seawater, and the material has good stability and reusability.

CN118045622BActive Publication Date: 2026-07-17HARBIN NORMAL UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HARBIN NORMAL UNIVERSITY
Filing Date
2024-03-05
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies are insufficient to efficiently reduce hexavalent uranium in seawater to solid tetravalent uranium under visible light. Furthermore, the reduced uranium is difficult to enrich and the resulting powder material is difficult to form, which has prevented breakthrough progress in seawater uranium extraction strategies.

Method used

A self-floating Znln2S4/CeO2/carbon sponge photocatalytic material was prepared by a one-step solubilization method to synthesize Znln2S4, a thermal deposition method to synthesize Znln2S4/CeO2, and finally Znln2S4/CeO2/CN. Uranium extraction from seawater was carried out under visible light conditions.

Benefits of technology

It achieves high efficiency in uranium extraction under visible light, reaching 13.2 mg/g. The material has good stability and retains more than 99% of its catalytic performance after recycling. The material can float freely on the sea surface, which enhances the value of uranium extraction from seawater.

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Abstract

本发明提出一种自漂浮Znln2S4 / CeO2 / 碳海绵光催化材料的制备方法及应用。所述自漂浮Znln2S4 / CeO2 / 碳海绵光催化材料的制备方法包括以下步骤:步骤一、利用一步溶热法合成Znln2S4;步骤二、利用热沉积法合成Znln2S4 / CeO2;步骤三、制备Znln2S4 / CeO2 / CN。具体步骤为:(1)Znln2S4 / CeO2的制备:将0.136克ZnCl2,0.586克InCl3‑4H2O和0.301克TAA加入含有60毫升去离子水的100毫升烧杯中,搅拌30分钟,形成悬浮液。将四个烧杯的悬浮液放入四个100毫升的高温高压反应器中,溶热阶段在433K下进行12小时。本发明提出的自漂浮Znln2S4 / CeO2 / 碳海绵光催化材料的制备方法工艺简单,能够在可见光条件下能够实现对海水提铀,解决了现有方法存在无法在六价铀还原为固体四价铀后,四价铀的富集以及现阶段还原铀的材料粉体无法成型的问题。
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