一种费托合成复合催化剂及其制备方法

By designing a three-layer composite catalyst, with a cobalt-based Fischer-Tropsch synthesis catalyst in the core, an alkane cracking catalyst in the middle layer, and an isomerization catalyst in the outer layer, the problem of low selectivity of aviation kerosene caused by the distribution of ASF in the traditional Fischer-Tropsch synthesis reaction was solved, and the preparation of C8-C16 fractions with high selectivity was achieved, thereby improving the reaction conversion rate and catalytic performance.

CN118106025BActive Publication Date: 2026-07-17INST OF COAL CHEM CHINESE ACAD OF SCI

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
INST OF COAL CHEM CHINESE ACAD OF SCI
Filing Date
2024-03-04
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The ASF distribution in traditional Fischer-Tropsch synthesis results in low selectivity for aviation kerosene, making industrial production difficult.

Method used

A three-layer composite catalyst is used, with a cobalt-based Fischer-Tropsch synthesis catalyst in the core, an alkane cracking catalyst in the middle layer, and an isomerization catalyst in the outer layer. By optimizing the structure and composition of the catalyst, a one-step catalytic synthesis gas process with high selectivity to produce C8-C16 fractions is achieved.

Benefits of technology

It improved the reaction conversion rate and target product selectivity of the catalyst, especially the selectivity of aviation kerosene, reduced the selectivity of methane, and enhanced the mechanical strength and hydrothermal stability of the catalyst.

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Abstract

本发明提供一种费托合成复合催化剂及其制备方法,属于催化剂技术领域。所述催化剂包括内核、中间层和外层;所述内核包括钴基费托合成催化剂,所述中间层包括烷烃裂解催化剂,所述外层包括异构化催化剂。其制备方法是将钴基费托合成催化剂的外层加载烷烃裂解催化剂,干燥固化后得到中间产物,再在所述中间产物的外层加载异构化催化剂,二次干燥固化后即得。本发明通过制备三层结构的复合催化剂并调节其结构及组成,可实现一步法催化合成气高选择性得到C8‑C16馏分,实现航空煤油的一步定向合成。
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