一种氢键有机框架材料HOF-TCNC2C的制备方法与应用

By constructing the hydrogen-bonded organic framework material HOF-TCNC2C, the problem of high time consumption, high energy consumption, and high cost in the separation and purification of C6-C7 carbon hydrocarbons has been solved, achieving efficient and low-cost separation and purification results.

CN118162108BActive Publication Date: 2026-07-17TIANJIN NORMAL UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
TIANJIN NORMAL UNIVERSITY
Filing Date
2023-11-15
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies for separating and purifying C6-C7 carbon hydrocarbons with similar physical properties are time-consuming, energy-intensive, and costly. They also lack highly selective adsorbents, making it difficult to achieve cost-effective and efficient separation and purification.

Method used

The hydrogen-bonded organic framework material HOF-TCNC2C is used to construct one-dimensional channels through CH…N hydrogen bonds, CH…π and van der Waals forces to achieve efficient separation and purification of C6-C7 carbon hydrocarbons.

Benefits of technology

The material is simple to prepare, has a short adsorption time, high purity, and can be reused multiple times. It is suitable for efficient separation of gases and liquids and meets the requirements of energy conservation and emission reduction.

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Abstract

本申请公开了一种氢键有机框架材料(HOF‑TCNC2C)及其制备方法和应用,属于超分子功能新材料技术领域。一种氢键有机框架材料HOF‑TCNC2C,所述HOF‑TCNC2C的化学式为C42H25N5;所述HOF‑TCNC2C包括有机配体TCNC2C;所述有机配体TCNC2C具有式I所示结构,所述HOF‑TCNC2C含有近似菱形一维孔道;所述一维孔道为C‑H…N氢键、C‑H…π和范德华力构建;HOF‑TCNC2C可通过孔径筛分和主客体之间的C‑H…π和范德华力弱相互作用实现C6~C7碳烃类物质的高效分离。所述HOF‑TCNC2C可多次循环使用,分离性能未出现明显降低;该材料制备过程简单,分离性能优异。
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