SiO2@Cu2GaBO5@TiO2微米球异质结光催化材料及光催化产氢和甲醛应用

By constructing Cu2GaBO5@TiO2 heterojunction photocatalytic materials on the SiO2 surface, the problem of poor light absorption capacity of TiO2 was solved, and efficient photocatalytic hydrogen production and formaldehyde production were achieved, thus broadening the application of borates in the field of photocatalysis.

CN118162136BActive Publication Date: 2026-07-17SHAANXI NORMAL UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHAANXI NORMAL UNIV
Filing Date
2023-11-15
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing TiO2 photocatalysts have a large band gap and poor light absorption capacity, and can only absorb ultraviolet light from sunlight, which limits their application in the field of photocatalysis. Furthermore, there is relatively little research on borate photocatalytic materials in the field of photocatalysis.

Method used

Using spherical SiO2 as a hard template, Cu2GaBO5 and TiO2 are coated on its surface through a two-step hydrothermal-pyrolysis method to construct a SiO2@Cu2GaBO5@TiO2 microsphere heterojunction photocatalytic material. The strong light absorption capacity and crystal structure distortion of Cu2GaBO5 promote electron transfer and broaden the utilization rate of visible light.

Benefits of technology

It achieves efficient photocatalytic hydrogen production and formaldehyde production. The photocatalytic hydrogen production of SiO2@Cu2GaBO5@TiO2 is several times that of SiO2@Cu2GaBO5 and Cu2GaBO5@TiO2, and methanol can be oxidized into formaldehyde, a high-value-added product.

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Abstract

本发明公开了一种SiO2@Cu2GaBO5@TiO2微米球异质结光催化材料及其光催化产氢和甲醛的应用。本发明以球形SiO2为硬模板,采用两步水热‑热解法制备了SiO2@Cu2SGaBO5@TiO2异质结光催化材料,制备方法简单,所得光催化材料由于采用球形SiO2作为硬模板避免样品团聚,利用Cu2GaBO5强的吸光性拓宽对可见光的吸收范围,和姜泰勒效应促进电子转移,提升在TiO2表面光催化质子还原反应能力。本发明以甲醇为牺牲剂,所得光催化材料不仅表现出优异的产氢活性,且甲醇可氧化成高附加值产品甲醛。
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