一种微胶囊复合灭火组合物及其制备方法与应用

By encapsulating liquid core material with modified montmorillonite to form a microcapsule composite fire extinguishing composition, which is then sprayed onto the inner wall of the lithium battery casing, the heat absorption and insulation properties of montmorillonite are utilized to form a Si-O bond flame retardant layer. The liquid core material decomposes to produce polyphosphoric acid and PO free radicals to isolate oxygen and form a char layer. This solves the problem that existing fire extinguishing agents cannot completely extinguish lithium battery fires, achieving the effect of complete extinguishing and preventing reignition.

CN118236665BActive Publication Date: 2026-07-17CHONGQING YUJIE FIRE FIGHTING EQUIP CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CHONGQING YUJIE FIRE FIGHTING EQUIP CO LTD
Filing Date
2024-02-04
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing fire extinguishing agents cannot completely extinguish lithium battery fires, which are prone to reignition. Methods such as physical dilution to isolate oxygen or interrupt the combustion chain are not very effective.

Method used

Modified montmorillonite is used to encapsulate liquid core material 1-butyl-3-methylimidazolium dibutyl phosphate to form a microcapsule composite fire extinguishing composition. This composition is then mixed with liquid epoxy resin, antioxidant, film-forming agent, and dispersant, and sprayed onto the inner wall of the lithium battery casing to form a fire extinguishing and protective coating. The heat absorption and insulation properties of montmorillonite are utilized to form a Si-O bond flame retardant layer. The liquid core material decomposes to produce polyphosphoric acid and PO free radicals to isolate oxygen and form PNP and POP chemical bonds to form a carbon layer.

Benefits of technology

It achieves complete extinguishing of lithium battery fires and prevents reignition. It protects the battery through multi-layer flame retardancy and oxygen isolation, and is halogen-free, environmentally friendly and safe.

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Abstract

本发明涉及一种微胶囊复合灭火组合物及其制备方法与应用。该制备方法包括:S1.向去离子水中加入蒙脱土悬浮液,搅拌加热后加入甲基笼型倍半硅氧烷,继续搅拌,得到混合物,抽滤,真空干燥,研磨,得到改性蒙脱土,将羟甲基纤维素钠和改性蒙脱土分散于去离子水中,得到壁材溶液;混合液态芯材和壁材溶液,搅拌,过滤,干燥,得到微胶囊,液态芯材包括1‑丁基‑3‑甲基咪唑磷酸二丁酯;S2.向去离子水中加入液态环氧树脂、抗氧化剂、成膜剂、分散剂和微胶囊,搅拌均匀。本发明能够改善灭火效果,且不含卤素等阻燃基团,安全环保。
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