一种难熔金属表面超高温抗烧蚀层状复合涂层及其制备方法

By preparing a layered composite coating consisting of a silicide rough transition layer and an ultra-high temperature carbide ceramic layer on the surface of refractory metals, and using chemical vapor deposition and slurry melting methods, the problems of easy loss and cracking of existing coatings at high temperatures were solved, and high-purity, high-density coatings were prepared, thus improving the ablation resistance of refractory metals.

CN118241182BActive Publication Date: 2026-07-17NORTHWEST INSTITUTE FOR NONFERROUS METAL RESEARCH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
NORTHWEST INSTITUTE FOR NONFERROUS METAL RESEARCH
Filing Date
2024-03-26
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing silicide coatings on refractory metal surfaces are easily lost at high temperatures, while ultra-high temperature carbide ceramic coatings have poor density and are prone to cracking. It is difficult to achieve high purity and high density on refractory metal surfaces, and the bonding strength with the substrate is insufficient.

Method used

Ultra-high temperature carbide ceramic layers were prepared by chemical vapor deposition, and a silicide rough transition layer was introduced on the surface of a refractory metal substrate. Metallurgical bonding was formed by slurry sintering. A layered composite coating structure was designed to improve bonding strength and thermal stability.

Benefits of technology

It has achieved high-purity and high-density preparation of ultra-high temperature carbide ceramic layers, which improves the ablation resistance of refractory metals and is suitable for oxidation and heat flow erosion environments above 1900℃, thus solving the problem of ultra-high temperature protection of refractory metals in aerospace devices.

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Abstract

本发明公开了一种难熔金属表面超高温抗烧蚀层状复合涂层及其制备方法,该涂层包括依次覆盖在难熔金属基体表面的硅化物粗糙过渡层和超高温碳化物陶瓷层;该涂层的制备方法包括:先对难熔金属表面进行预处理,再采用料浆熔烧法在难熔金属表面制备硅化物粗糙过渡层,然后采用化学气相沉积法低温制备高纯度、高致密度的超高温碳化物陶瓷层;本发明的层状复合涂层通过在难熔金属基体与超高温碳化物陶瓷层之间引入硅化物粗糙过渡层,使得涂层与基体之间具有良好的结合性能,该层状复合涂层的热稳定性高,并具有超高温抗烧蚀性能,在1900℃以上冲刷烧蚀环境下可为难熔金属提供有效防护,适用于航空航天飞行器发动机部件及前缘、鼻锥等。
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