一种微波固化制备YAG基透明陶瓷的方法

By combining microwave curing technology with nonpolar polymer catalysts, efficient, safe, and integrated molding of YAG-based transparent ceramics has been achieved, solving the problems of long preparation cycles and high costs in traditional methods. This method is suitable for the preparation of transparent ceramics with irregular shapes.

CN118290147BActive Publication Date: 2026-07-17XINYI XIYI ADVANCED MATERIALS RES INST OF IND TECH CO LTD +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
XINYI XIYI ADVANCED MATERIALS RES INST OF IND TECH CO LTD
Filing Date
2024-04-03
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies are insufficient for the efficient and low-cost preparation of YAG-based transparent ceramics, especially irregularly shaped transparent ceramics. Furthermore, traditional methods suffer from long preparation cycles, complex equipment, and poor safety.

Method used

YAG-based transparent ceramics were prepared using microwave curing technology. The polymerization reaction of the ceramic slurry was initiated by microwave radiation, and combined with the non-polar polymer catalyst tetramethylpiperidine nitric oxide radical, rapid gelation and shaping were achieved, which simplified the preparation process and avoided the hindrance of oxidative polymerization.

Benefits of technology

This method enables efficient, safe, and integrated molding of YAG-based transparent ceramics, shortens the preparation cycle, reduces production costs, solves the preparation problems in traditional methods, and improves the safety and controllability of microwave curing.

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Abstract

一种微波固化制备YAG基透明陶瓷的方法,包括:以Al2O3和Y2O3、或者Al2O3、Y2O3和稀土氧化物作为原料,按化学式Y3Al5O12或(Y1‑xRex)3Al5O12中对应元素的化学计量比称取各原料,加入柠檬酸和去离子水得到陶瓷浆料;将陶瓷浆料球磨后加入丙烯酰胺,再加入N,N’亚甲基双丙烯酰胺和四甲基哌啶氮氧自由基进行滚筒球磨;再加入偶氮二丁腈进行脱泡;再依次经过微波固化、干燥、煅烧、真空烧结、退火后得到YAG基透明陶瓷。该方法可缩短凝胶注膜成型的凝胶期,大幅度缩短透明陶瓷的制备过程,降低生产成本,且氧阻聚效应对固化成型方案无明显阻碍现象,能实现异形结构透明陶瓷的一体化成型与高效生产。
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