一种富硅LTA分子筛膜的快速合成方法及应用

By adjusting the alkalinity of the reaction sol and adding seed crystals to induce crystal formation, the crystallization process of silicon-rich LTA molecular sieve membranes was optimized, solving the problems of long synthesis time and high energy consumption. This resulted in efficient membrane synthesis and excellent pervaporation performance, making it suitable for organic solvent separation under high temperature and high hydrothermal conditions.

CN118324155BActive Publication Date: 2026-07-17JIANGXI NORMAL UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
JIANGXI NORMAL UNIV
Filing Date
2024-04-10
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing silicon-rich LTA molecular sieve membranes suffer from problems such as excessively long synthesis time, low utilization rate of reaction equipment, and high energy consumption, which limit their industrial application in organic solvent dehydration processes.

Method used

By employing multiple strategies, including adjusting the alkalinity of the reactive sol, adding seed crystals for induction, and controlling the synthesis temperature, the crystallization process of silicon-rich LTA molecular sieve membranes was optimized, shortening the synthesis time and improving the membrane's high-temperature stability and pervaporation performance.

Benefits of technology

The synthesis time of silicon-rich LTA molecular sieve membranes was significantly shortened to 1/4, reducing energy consumption and improving the utilization rate of reaction equipment. A membrane with excellent pervaporation performance was obtained, which is suitable for the separation of organic solvents under high temperature and high hydrothermal conditions.

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Abstract

本发明涉及一种富硅LTA分子筛膜的快速合成方法,包括以下步骤:向铝源中加入去离子水后,再加入碱源升温搅拌,铝源完全溶解后滴加硅源,获得合成溶胶,将合成的富硅LTA晶种超声分散于溶剂中,形成晶种悬浮液,再通过真空抽涂法获得晶种化支撑体。将原料混合后剧烈搅拌形成乳白色溶胶,经过老化处理后得到分子筛膜合成溶胶;在分子筛膜合成溶胶老化结束前10min时,加入晶种,并加入晶种化支撑体,通过加热进行水热晶化反应,反应完成后,得到富硅LTA分子筛膜。本发明提供了一种在含氟溶胶体系下通过调节反应溶胶碱度以及合成温度并添加晶种诱导等多重策略来加速富硅LTA分子筛膜晶体的晶化速度,可以大幅度减少分子筛膜的反应时间。
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