一种固态胺吸附剂的制备方法、固态胺吸附剂及其在超低压CO2吸附中的应用

By preparing solid amine adsorbents, the problems of high cost, difficult regeneration, and difficulty in low-pressure CO2 adsorption of existing adsorbents have been solved, achieving efficient and low-cost CO2 adsorption and separation, especially exhibiting excellent CO2 adsorption performance and stability under ultra-low pressure conditions.

CN118341399BActive Publication Date: 2026-07-17JIANGSU UNIV OF SCI & TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
JIANGSU UNIV OF SCI & TECH
Filing Date
2024-05-21
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing adsorbents are costly and difficult to regenerate, making it difficult to achieve low-pressure CO2 adsorption and capture, especially under ultra-low pressure conditions. Furthermore, the process of liquid amine absorbing CO2 is energy-intensive and highly corrosive.

Method used

A solid amine adsorbent was prepared by mixing silicon powder with NaOH solution to obtain sodium silicate solution, then mixing it with polyvinylpyrrolidone solution, treating it in a high-temperature and high-pressure autoclave, calcining it, and impregnating it with tetraethylenepentamine solution to obtain the solid amine adsorbent.

Benefits of technology

The prepared solid amine adsorbent has a high CO2 adsorption capacity under ultra-low pressure, reaching 1.50 mmol g-1 at 0.01 bar, which is 6.8 times higher than the adsorption capacity. It also has good thermal stability and regeneration ability, making it suitable for high-temperature adsorption-desorption processes. It is low in cost and environmentally friendly.

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Abstract

本发明公开了一种固态胺吸附剂的制备方法及固态胺吸附剂,所述制备方法以工业废弃物硅粉为原料,以四乙烯五胺作为改性剂,通过分步多次浸渍加热,制得固态胺吸附剂。所制得的吸附剂对CO2吸附性能较高,尤其在超低压条件下,当压力低于0.01bar时,CO2吸附容量随着压力的增加而激增,当达到0.01bar时最大的CO2吸附容量为1.50mmol g‑1,随后CO2吸附等温线则变得相对平缓。最大的CO2吸附容量为2.22mmol g‑1,对CO2的吸附能力相较未负载TEPA的原始材料提升了6.8倍,且在常温下对于CO2 / N2具有极高的选择吸附性。本发明制得的吸附剂还具有良好热稳定性,适用于高温下的吸附‑脱附过程,并且表现出出色的稳定性和再生能力。
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