一种非选择性硫基重金属挑出稳定剂及其制备方法和应用

By using a non-selective sulfur-based heavy metal pickering stabilizer in waste incineration fly ash and utilizing gas-solid reaction to block dioxin formation, the problem of harmless treatment of heavy metals and dioxins has been solved, achieving efficient and low-cost harmless treatment of fly ash.

CN118384472BActive Publication Date: 2026-07-17HUBEI UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HUBEI UNIV
Filing Date
2024-04-09
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies are insufficient to effectively reduce the formation of heavy metals and dioxins in fly ash from waste incineration, resulting in high costs for harmless treatment and making large-scale application difficult.

Method used

A non-selective sulfur-based heavy metal picker is used, and desulfurized ash pretreated by oxidation is used as a carrier. It combines components such as triethanolamine, calcium formate and star-shaped hyperbranched polymer to carry out gas-solid reaction in the combustion chamber, so as to achieve indiscriminate sulfurization and fixation of heavy metals and block the formation of dioxins.

Benefits of technology

It achieves a heavy metal removal efficiency of over 95%, reduces dioxin toxicity by two orders of magnitude, is inexpensive, suitable for large-scale promotion and application, and avoids secondary pollution.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明涉及环境保护技术领域,具体涉及一种市政垃圾焚烧飞灰无害化处理过程中使用的重金属挑出稳定剂及其应用。该稳定剂由氧化预处理半干法SDA脱硫灰为载体、三乙醇胺联合甲酸钙为活化助剂、硫脲为芯的具有羧酸钠侧基及二硫代羧酸钠端基的星形超支化聚合物及亚烷基二胺四二硫代羧酸钠有效挑出组分组成,其中硫脲为芯的具有羧酸钠侧基及二硫代羧酸钠端基的星形超支化聚合物的化学式为:N[CH2CH2OCOCH2CH2(COONa)N(O3S2Na2)CH2(CH2)nCH2N(CSSNa)2]3,亚烷基二胺四二硫代羧酸钠化学式为:(Na2SSO3)2NCH2(CH2)nCH2N(O3SSNa2)2,n为0~4之间的正整数。该稳定剂可以在成本较低的情况下实现垃圾焚烧飞灰的无害化处理。
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