Hollow core-shell structure resin@tio2 composite material, its preparation method and application

By using a hollow core-shell structured resin@TiO2 composite material, the problems of high cost and instability in halogen wastewater treatment have been solved, achieving efficient and harmless treatment of halogens and long-term stable storage of the material.

CN118384866BActive Publication Date: 2026-06-23SHAANXI LANGSHI DENI NEW MATERIAL TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHAANXI LANGSHI DENI NEW MATERIAL TECH CO LTD
Filing Date
2024-04-29
Publication Date
2026-06-23

AI Technical Summary

Technical Problem

Existing technologies for treating halogen wastewater suffer from high treatment costs, technical difficulties, and unstable treatment results, leading to the need for multiple reprocessing of treated materials and potential environmental corrosion.

Method used

A resin@TiO2 composite material with a hollow core-shell structure is used to efficiently remove halogens through an electrophilic substitution reaction. The stability of the TiO2 shell is used to avoid corrosion between the material and metals or plastics. The composite material with uniform particles and good hydrophilicity is prepared by sol-gel method.

Benefits of technology

It achieves efficient and harmless treatment of halogens, and the material is stable at room temperature for a long time. It is suitable for storage in metal or plastic containers, reducing treatment costs and improving the stability of treatment results.

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Abstract

The present application relates to a kind of hollow core-shell structure resin TiO2 Composite material and its preparation method and application in long-term protection of zinc sheet against bromine corrosion after removing bromine iodine halogen element, resin nanoparticles synthesized by phenol and aldehyde as matrix, through structural engineering design, using low-temperature room pressure sol-gel method, in water and alcohol mixed solution system, namely, can obtain the uniform size, good hydrophilic and water dispersibility, environmental compatibility and low-cost hollow core-shell structure resin TiO2 Composite material.The composite material prepared in the application can be used as bromine iodine adsorption material, and bromine iodine and derivatives in wastewater can be effectively adsorbed and removed;And hollow core-shell structure resin TiO2 Composite material has strong structural stability and corrosion resistance, after bromination, material shell can prevent direct contact with other materials, effectively applied to metal, plastic corrosion protection, convenient to recycle long-term in conventional metal, plastic container.
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