一种具有自蒙囿作用的水滑石纳米无铬鞣剂及其制备方法和应用

By preparing oxidized polysaccharide-coated hydrotalcite nano-chromium-free tanning agents, the problem of poor dispersibility of hydrotalcite in leather is solved, achieving uniform tanning and improved wet heat resistance of leather, avoiding chromium pollution, and having both environmental and economic benefits.

CN118389754BActive Publication Date: 2026-07-17SHAANXI UNIV OF SCI & TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHAANXI UNIV OF SCI & TECH
Filing Date
2024-05-29
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing hydrotalcites (LDHs) have poor dispersibility in leather collagen, resulting in decreased leather uniformity and difficulty in penetrating into the collagen fibers, thus affecting the quality of the finished leather.

Method used

A hydrotalcite nano-chromium-free tanning agent was prepared by mixing an oxidized polysaccharide solution with a mixture of magnesium, aluminum, and metal A nitrates. A special structure of oxidized polysaccharide-coated LDHs was constructed by oxidation reaction and pH control, which slowed down the binding rate with the skin surface, improved dispersibility, and generated covalent cross-linking between the functional groups in the oxidized polysaccharide solution and the skin collagen side chains.

Benefits of technology

This method achieves uniform dispersion of hydrotalcite nano-chromium-free tanning agents in leather, improves the wet heat resistance and sensory properties of the finished leather, and solves the chromium pollution problem, resulting in significant environmental and economic benefits.

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Abstract

本发明公开了一种具有自蒙囿作用的水滑石纳米无铬鞣剂及其制备方法和应用,属于皮革鞣制技术领域。本发明公开的方法,通过氧化多糖溶液作为原料,与其余材料协同作用,构建氧化多糖包覆LDHs的特殊结构,氧化多糖溶液可充当LDHs在鞣制过程中的蒙囿剂,减缓LDHs与皮表面的结合速率,提高LDHs在皮胶原纤维中的分散性。采用上述方法得到的自蒙囿作用的水滑石纳米无铬鞣剂,重均分子量为3000‑15000g / mol,多分散系数为1.5~2.5,具有良好的应用前景。
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