一种由糖类化合物、二氧化碳和氢气反应合成多碳羧酸的方法

By using a catalytic system of rhodium catalyst and iodine co-catalyst, a method for generating multi-carbon carboxylic acids through the coupling reaction of carbohydrates with carbon dioxide and hydrogen is achieved. This method overcomes the shortcomings of existing technologies in converting carbohydrates and carbon dioxide into high-value chemicals and realizes a highly efficient method for converting them into multi-carbon carboxylic acids.

CN118403663BActive Publication Date: 2026-07-17INST OF CHEM CHINESE ACAD OF SCI

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
INST OF CHEM CHINESE ACAD OF SCI
Filing Date
2023-01-30
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the existing technology, the methods for synthesizing high-value chemicals by reacting sugars such as glucose with carbon dioxide have not been fully developed. The production pathways for multi-carbon carboxylic acids are limited, and there is a huge price difference between raw materials and products, with a lack of effective conversion methods.

Method used

A catalytic system employing a rhodium catalyst, iodine as a co-catalyst, and a binary solvent composed of carboxylic acids and water generates multicarbon carboxylic acids through a coupling reaction of carbohydrates with carbon dioxide and hydrogen.

Benefits of technology

This technology enables the conversion of inexpensive renewable resources such as carbohydrates and carbon dioxide into high-value-added multi-carbon carboxylic acids, opening up new avenues for biomass utilization and carbon dioxide conversion. The resulting multi-carbon carboxylic acid product has broad application prospects.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明公开了一种由糖类化合物、二氧化碳和氢气反应合成多碳羧酸的方法。本发明提供的多碳羧酸的制备方法,包括如下步骤:在催化体系作用下,糖类化合物、二氧化碳和氢气进行偶联反应,得到所述多碳羧酸。所述催化体系由主催化剂、助催化剂和二元溶剂组成;所述主催化剂为铑催化剂;所述助催化剂为I2;所述二元溶剂由羧酸和水组成。本发明首次提出了由糖类化合物与二氧化碳、氢气反应合成多碳羧酸的反应路线,开辟了生物质利用和二氧化碳转化利用的新途径。由于糖类化合物、二氧化碳均为价廉易得的可再生碳资源,所得产品多碳羧酸为高附加值的重要化学品,产品和原料之间存在巨大的价格差异,因而该方法具有更好的应用前景。
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