一种尺寸可调的高质量碲化锌(ZnTe)量子点的制备方法

By using highly active aminophosphine ligands and a gradient-controlled secondary growth method, the problem of uneven size distribution of ZnTe quantum dots was solved, and high-quality, size-tunable ZnTe quantum dots were prepared, improving their optical performance and synthesis reproducibility in the blue-green light range.

CN118419863BActive Publication Date: 2026-07-17JILIN UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
JILIN UNIVERSITY
Filing Date
2024-04-23
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies cannot effectively control the size distribution and morphology of ZnTe quantum dots, resulting in poor synthesis reproducibility and failing to meet the requirements for optical bandgap control in the blue-green light range.

Method used

Using highly reactive aminophosphorus as an anionic ligand, the size distribution of ZnTe quantum dots was controlled by a one-step high-temperature thermal injection method and a secondary growth method. The aminophosphorus was used to enhance the reactivity of tellurium ions, and the reactivity of tellurium and zinc precursors was reduced by gradient, thus realizing the preparation of monodisperse ZnTe quantum dots of different sizes.

Benefits of technology

High-quality ZnTe quantum dots with uniform size and tunable particle size were successfully prepared, solving the problems of uneven size distribution and poor synthesis reproducibility, and expanding the optical bandgap control capability of ZnTe quantum dots in the blue-green light range.

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Abstract

本发明涉及半导体材料技术领域,尤其涉及一种尺寸可调的高质量碲化锌(ZnTe)量子点的制备方法,本发明通过使用高活性前驱物,改变阳离子和阴离子的反应活性,利用魔力尺寸团簇到量子点转化和多次注入前驱物外延生长相结合的方法,实现了ZnTe量子点成核和生长过程的分离,合成出不同尺寸的ZnTe量子点,本发明提供了一种系统便捷简单的尺寸可调的高质量ZnTe量子点的制备方法,成功制备了不同尺寸的单分散的ZnTe量子点,对合成ZnTe半导体量子点和后续基于ZnTe化合物量子点光电器件的应用具有重要意义。
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