用于废SCR催化剂回收载体的脱铁方法及脱铁载体和应用

By treating the waste SCR catalyst support using induced alkaline leaching and reduction-complexation methods, the problem of iron removal was solved, the structure and activity of the support were restored, and efficient iron removal and removal of harmful impurities were achieved, meeting the requirements for the use of SCR catalysts.

CN118437413BActive Publication Date: 2026-07-17CHINA ENERGY INVESTMENT CORP LTD +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CHINA ENERGY INVESTMENT CORP LTD
Filing Date
2023-02-06
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies are insufficient to effectively remove iron from the recovery support of spent SCR catalysts, resulting in excessively high iron content in the support, which affects the SO2/SO3 conversion rate and service life of the SCR catalyst.

Method used

By employing an induced alkaline immersion modification combined with a reduction-complexation method, an insoluble sodium titanate nano-carrier surface is generated, restoring the specific surface area and pore volume. Furthermore, ferric iron is reduced to ferrous iron to form a stable complex that dissolves in the liquid phase, thereby achieving deep removal of iron and harmful impurities.

Benefits of technology

It significantly improved the iron removal efficiency to over 95%, restored the structure and activity of the support, met the standards for SCR catalysts, and extended its service life.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明提供一种用于废SCR催化剂回收载体的脱铁方法,包括以下步骤:(1)向废SCR催化剂回收载体中加入诱导剂和碱溶液进行改性反应,然后固液分离,得到第一液体和作为改性物料的第一固体;(2)向步骤(1)所得第一固体中加入酸溶液调节体系的pH,然后向体系中加入还原剂和络合剂进行络合反应,然后固液分离,得到第二液体和作为脱铁物料的第二固体;(3)对步骤(2)所得第二固体依次进行清洗、干燥和煅烧,获得脱铁载体。还提供所得脱铁载体及其应用。该脱铁方法,能够较方便地将废SCR催化剂回收载体中的铁分离除去。所得脱铁载体中,铁含量较小。
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