淀粉基硬碳负极活性材料及其制备和在钠离子电池中的应用

By combining starch raw materials with three-stage controlled gas heat treatment and co-pre-oxidation raw materials, the foaming problem in the preparation process of starch-based anode materials was solved, realizing the efficient application of starch-based hard carbon materials in sodium-ion batteries and improving the fast charging and high-rate long-range cycle performance of the materials.

CN118458748BActive Publication Date: 2026-07-17CENT SOUTH UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CENT SOUTH UNIV
Filing Date
2024-06-05
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Starch-based anode materials are prone to foaming during preparation, making them difficult to adapt to the requirements of fast charging and high-rate long-term cycling. Existing methods suffer from problems such as long preparation time, high cost, and complex processes.

Method used

A mixture of starch raw materials and co-pre-oxidized raw materials is used, and a three-stage controlled-atmosphere heat treatment is performed: a combination of oxygen-containing atmosphere, carbon dioxide-containing atmosphere and protective atmosphere. This optimizes the physicochemical structure of starch-based materials and improves the storage capacity and transport pathway of sodium ions.

Benefits of technology

A starch-based hard carbon material suitable for fast charging and high-rate long-range cycling stability was prepared, which improved the performance of sodium-ion batteries, especially the first-cycle discharge specific capacity and cycle stability.

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Abstract

本发明涉及钠离子电池技术领域,具体公开了一种淀粉基硬碳负极活性材料及其制备和在钠离子电池中的应用;制备过程包括一种淀粉基负极活性材料的多段控气制备方法,首先将包含淀粉原料、共预氧化原料的混合原料预先在含氧气氛中进行第一段热处理,随后在含二氧化碳气氛中进行第二段热处理,再在保护性气氛中进行第三段热处理,制得所述的淀粉基负极活性材料。上述制备方法基于淀粉原料获得近球形、高性能的钠离子电池硬碳负极材料。本发明技术具有抑制淀粉膨胀、提高产碳率、提高平台储钠容量、适配快充以及高倍率长程循环稳定性、方法简单、过程可控、成本低廉等优点。
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