Ultra-high-yield molecular sieve, preparation method and application thereof
By preparing the iron source in a non-aqueous system, the oxidation of Fe2+ to Fe3+ and the introduction of inorganic alkali metal cations are avoided, thus solving the problems of low yield and insufficient catalytic activity of iron-based molecular sieves and realizing efficient molecular sieve preparation and application.
CN118495550BActive Publication Date: 2026-07-03SHAANXI COAL & CHEM TECH INST
Patent Information
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- SHAANXI COAL & CHEM TECH INST
- Filing Date
- 2024-05-08
- Publication Date
- 2026-07-03
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Figure CN118495550B_ABST
Abstract
This invention provides an ultra-high yield molecular sieve, its preparation method, and its application. The method includes: mixing [C] in a molar ratio of (0.5–2.5):1. n Heating a mixture of mim]R and FeZ2 yields an iron source [xC] n mim][FeZ2R x [The following text appears to be a separate, unrelated section:] Where n≥2, x=0.5~2.5, R and Z are both Cl ions or Br ions; An alkali source, structure directing agent, aluminum source, iron source, and silicon source are added to water and stirred evenly to obtain a gel, which is then subjected to hydrothermal crystallization to synthesize the product; the product is washed and dried, and then calcined to remove the structure directing agent to obtain a molecular sieve with ultra-high yield. This invention avoids the Fe... 2+ Oxidized to Fe 3+ This invention does not introduce inorganic alkali metal cations, and the prepared molecular sieve has better catalytic activity. It improves the product yield and raw material utilization of molecular sieves, reduces the difficulty of treating molecular sieve synthesis waste liquid, controls costs, and has practicality.
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