盐湖提锂用全固态聚合物微颗粒、其制备方法及提锂方法

By preparing all-solid polymer microparticles containing phenylazonaphthol and neutral ligands, the stability and solubility problems of the Sudan I extraction system were solved, realizing efficient and environmentally friendly lithium adsorption extraction, which is suitable for lithium extraction from salt lake brine.

CN118513012BActive Publication Date: 2026-07-17QINGHAI UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
QINGHAI UNIVERSITY
Filing Date
2024-05-14
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The existing phenylazonaphthol extraction system, represented by Sudan I, suffers from problems such as poor chemical stability of the extractant, low solubility, poor dissolving ability, and the need for large amounts of organic solvent dilution, leading to solvent loss and environmental pollution. Therefore, it cannot be effectively applied to industrial lithium extraction.

Method used

All-solid polymer microparticles containing phenylazonaphthol and neutral ligands were prepared using microfluidic technology. Lithium adsorption polymer microparticles were prepared in a good solvent by in-situ phase separation method, realizing solid-liquid mass transfer and avoiding the use of additional organic solvents. The all-solid microparticles were prepared by utilizing the solidification and precipitation characteristics of polymers in the aqueous phase.

Benefits of technology

This invention enables efficient lithium extraction in an alkaline environment, avoids the use and loss of organic solvents, simplifies the extraction process, provides a green and efficient lithium adsorbent, and expands the types and applications of adsorbents.

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Abstract

一种盐湖提锂用全固态聚合物微颗粒、其制备方法及提锂方法,涉及盐湖化工技术领域,利用少量良溶剂构筑高分子聚合物与苯基偶氮萘酚和中性配体以合适的比例组成的混溶体系,然后采用以微流控为代表的技术利用聚合物与苯基偶氮萘酚和中性配体原位相分离方法制备全固态包含苯基偶氮萘酚和中性配体的锂吸附用聚合物微颗粒,最后利用该固态微颗粒实现从盐湖卤水中提锂的应用方法。本发明的有益效果在于:本发明所制备的聚合物微颗粒在锂吸附提取过程中,将锂萃取过程的液液传质转变为固液传质,从而不需要使用任何额外的有机溶剂作为稀释剂,使用方便,为盐湖高效提锂提供了一种绿色高效的全固态聚合物吸附剂,为碱性环境提锂提供了一种新方法。
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