一种纳米多金属铁酸盐催化剂及其制备方法和应用

The nano-polymetallic ferrite catalyst prepared by high-temperature solid-phase reaction and magnetic separation technology solves the problems of low yield, high cost and narrow temperature window of existing nano-ferrite catalysts in carbon reduction and denitrification processes, and realizes efficient and low-cost CO2 reduction and NOx reduction, which is suitable for industrial flue gas treatment.

CN118513049BActive Publication Date: 2026-07-17CENT SOUTH UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CENT SOUTH UNIV
Filing Date
2024-05-10
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing nano-ferrite catalysts suffer from low yield, high cost, limited CO2 reduction capacity, narrow operating temperature window, and the need for secondary heating for denitrification during carbon reduction and denitrification processes, making industrial application difficult.

Method used

Using inexpensive and readily available natural minerals and solid waste as raw materials, a nano-polymetallic ferrite catalyst with strong magnetic properties and high catalytic activity is synthesized through high-temperature solid-phase reaction. Magnetic separation and nano-sand milling technology are used to achieve the nano-sizing and efficient preparation of the catalyst, thereby broadening the CO2 reduction temperature range and reducing the denitrification temperature.

Benefits of technology

It achieves efficient and low-cost CO2 reduction to solid carbon and selective NOx reduction to N2. The catalyst can directly utilize the waste heat of the factory flue gas, reducing the need for additional heating, improving CO2 reduction and denitrification efficiency, and is suitable for industrial production.

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Abstract

本发明公开了一种纳米多金属铁酸盐催化剂及其制备方法和应用。将包括铁源、锰源、镁源、钙源、硅源和铬源在内的原料依次经过破碎、球磨、配料、压块、焙烧、球磨、磁选和纳米砂磨,即得纳米多金属铁酸盐催化剂,将其应用于低温烟气脱硝或二氧化碳还原转化时,能实现低温(200~400℃)循环催化还原CO2为固体碳,或者能实现超低温(100~150℃)烟气中持续、高效地选择性催化还原NOx为N2,且纳米多金属铁酸盐催化剂的制备成本低、高效率,可以规模化制备,在烟气治理领域具有良好的应用前景。
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