一种氮掺杂碳量子点及其制备方法与应用

Nitrogen-doped carbon quantum dots were prepared by a hydrothermal method using betaine hydrochloride and ethylenediamine as raw materials. This method solved the problems of large particle size and high detection limit of existing carbon quantum dots when detecting copper ions, and enabled rapid, sensitive and low-cost detection of copper ions.

CN118580857BActive Publication Date: 2026-07-17HEBEI UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HEBEI UNIVERSITY
Filing Date
2024-05-17
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing carbon quantum dots have problems with large particle size and high detection limit in detecting copper ions, making it difficult to achieve rapid, accurate and specific detection.

Method used

Nitrogen-doped carbon quantum dots were prepared by a one-step, environmentally friendly hydrothermal method using betaine hydrochloride as the carbon source and ethylenediamine as the nitrogen source. The particle size was approximately 7.40 nm, and the fluorescence emission wavelengths were located at 456 nm and 520 nm, exhibiting excellent selectivity and sensitivity.

Benefits of technology

It enables rapid and sensitive detection of copper ions with a detection limit as low as 4.9 nmol/L, and emits light stably within the pH range of 3-11. It is simple to operate, low in cost, and requires minimal equipment, making it suitable for the detection of practical samples.

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Abstract

本发明提供一种氮掺杂碳量子点及其制备方法与应用,所述氮掺杂碳量子点是以甜菜碱盐酸盐为碳源,以乙二胺为氮源,采用绿色环保的一步水热法制备而成。本发明制备方法对设备要求低,操作简单,产物收率高。所制备碳量子点水溶性良好、稳定性高、荧光性质优异,对铜离子(Cu2+)具有优异的选择性,检出限为4.9nmol / L,干扰离子的存在几乎不影响CQDs对Cu2+荧光响应的灵敏度。本发明以该CQDs为荧光探针建立了Cu2+的快速检测方法,该方法具有简单快速、不需复杂仪器设备、实验成本低及环境友好等优势,可用于实际样品中Cu2+的快速、灵敏检测。
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