一种海泡石基催化剂新材料、制备方法及其在中低温SCR脱硝中的应用

Mn oxide supported catalysts were prepared by acidification with hydrochloric acid or nitric acid and freeze-drying, which solved the problems of catalyst inhomogeneity and calcium salt blockage caused by high-temperature calcination and sulfuric acid acidification in the prior art, and achieved high efficiency, stability and economy of medium and low temperature SCR denitrification.

CN118616039BActive Publication Date: 2026-07-17GUANGXI UNIV FOR NATITIES +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
GUANGXI UNIV FOR NATITIES
Filing Date
2024-05-29
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing medium- and low-temperature SCR denitration catalysts are prone to sintering during high-temperature calcination, resulting in uneven distribution of active components. In-situ growth methods may damage the support structure, and sulfuric acid acidification can lead to calcium salt precipitation and blockage, affecting catalyst activity.

Method used

A Mn oxide supported catalyst was prepared by acidifying sepiolite with hydrochloric acid or nitric acid, combined with freeze-drying and neutralization with an inorganic weak base. This method avoids high-temperature calcination, enhances the support structure and the dispersibility of the active components, and improves the specific surface area and redox performance of the catalyst.

Benefits of technology

It achieves efficient denitrification at medium and low temperatures, has a wide catalyst activity range, good sulfur resistance, reduces the denitrification temperature, improves the stability and economy of the catalyst, and avoids the problems of high-temperature sintering and calcium salt poisoning.

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Abstract

本发明公开了一种海泡石基催化剂新材料、制备方法及其在中低温SCR脱硝中的应用,属于烟气脱硝领域。其制备方法是以海泡石为载体,经酸活化处理后,采用冷冻干燥辅助原位生长法将Mn氧化物活性组分负载到酸化海泡石上,制备了具有优异中低温脱硝性能的脱硝催化剂。本发明的制备方法具有简单易操作、易工业化、经济环保、不需要添加有机高分子等优点,可以显著降低成本,具有良好的应用前景。
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