Single-prevention single-suction comfortable fabric manufacturing process and shirt

CN118617815BActive Publication Date: 2026-08-18HENAN GEORGE WHITE CLOTHING CO LTD
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Patent Information

Application Number
CN202410787540.2
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2024-06-18
Publication Date
2026-08-18
Estimated Expiration
2044-06-18

AI Technical Summary

Technical Problem

[0002]在夏天,衬衫、T恤是人们最常穿的服装,众所周知,在炎热的夏季,温度很高,人很容易出汗,在汗干了之后,在衣服上会出现汗痕,汗痕呈白色且有明显边缘痕迹,会影响服装的美观,也会让人感到尴尬,而且很容易使衣服泛黄,大大降低服装的使用寿命,现有技术中的服饰的防汗迹效果不好

Benefits of technology

本发明所提供的单防单吸舒适布料制造工艺,所述布料包括亲水内层和疏水外层,通过制作亲水内层纱线和疏水外层纱线,分别制成亲水内层和疏水外层,贴肤层亲水,快速吸汗,迅速蒸发,穿着更舒适,外层疏水,反向不渗透,形成保护屏障,汗液阻断,不显流汗痕迹,亲水内层原料中加入改性蛛丝纤维和改性甘露聚糖,二者协同增效,能够极大的提高布料吸湿排汗效果,疏水外侧原料中加入改性玉米朊和槲皮素,二者协同增效,能够极大的提高布料的防水效果。

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Abstract

The application is suitable for the technical field of clothes, and provides a single-prevention single-absorption comfortable fabric manufacturing process and a shirt.The fabric comprises a hydrophilic inner layer and a hydrophobic outer layer, and the manufacturing process comprises the following steps: manufacturing hydrophilic inner layer yarn; manufacturing hydrophobic outer layer yarn; weaving the hydrophilic inner layer yarn and the hydrophobic outer layer yarn into a fabric; completely immersing the fabric in clean water to perform rinsing; placing the rinsed fabric into a dehydration machine to perform dehydration treatment; placing the dehydrated fabric into a dye vat to perform dyeing treatment, and performing reduction cleaning after completion; performing setting through a setting machine; obtaining finished fabric by winding and packaging the set fabric through a winding machine, the hydrophilic inner layer yarn and the hydrophobic outer layer yarn are manufactured to form the hydrophilic inner layer and the hydrophobic outer layer respectively, the skin layer is hydrophilic, sweat is quickly absorbed and evaporated, wearing is more comfortable, the outer layer is hydrophobic, reverse non-permeation is formed, a protective barrier is formed, sweat is blocked, and sweat marks are not obvious.
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Description

Technical Field

[0001] This invention belongs to the field of clothing technology, and in particular relates to a manufacturing process for a single-layer absorbent and breathable comfortable fabric and a shirt. Background Technology

[0002] In summer, shirts and T-shirts are the most commonly worn clothing. As we all know, in the hot summer, the temperature is very high and people sweat easily. After the sweat dries, sweat stains will appear on the clothes. Sweat stains are white and have obvious edge marks, which will affect the appearance of the clothing and make people feel embarrassed. Moreover, they can easily cause the clothes to yellow and greatly reduce the lifespan of the clothing. Existing technology for clothing is not very effective at preventing sweat stains. Summary of the Invention

[0003] This invention provides a manufacturing process for a single-layer absorbent and breathable comfortable fabric, aiming to solve the above-mentioned problems.

[0004] This invention is achieved through a manufacturing process for a single-layer waterproof and absorbent comfortable fabric, wherein the fabric comprises a hydrophilic inner layer and a hydrophobic outer layer, and the manufacturing process includes the following steps: To produce a hydrophilic inner layer yarn; To produce a hydrophobic outer layer yarn; The hydrophilic inner layer yarn and the hydrophobic outer layer yarn are woven into a fabric using existing conventional techniques, which will not be described in detail here. Completely immerse the fabric in clean water and rinse it 2-3 times, each rinsing time being 5-10 minutes. After washing, put the fabric into a spin dryer for 10-20 minutes to dehydrate it. After dehydration, take it out and lay it flat on a drying rack. The dehydrated fabric is placed in a dyeing vat for dyeing treatment, and then subjected to reduction cleaning. Both the dyeing treatment and reduction cleaning are performed using existing conventional techniques. The shape is set using a setting machine, employing existing conventional technology; The finished fabric is obtained by rolling and packaging the shaped fabric using a rolling machine.

[0005] Preferably, the hydrophilic inner layer comprises the following raw materials in parts by weight: 20-30 parts bamboo fiber, 3-7 parts modified spider silk fiber, 6-12 parts polylactic acid fiber, 2-6 parts chitosan fiber, 1-5 parts modified mannan, and 10-15 parts flax fiber.

[0006] Preferably, the hydrophilic inner layer comprises the following raw materials in parts by weight: 23-27 parts bamboo fiber, 4-6 parts modified spider silk fiber, 8-10 parts polylactic acid fiber, 3-5 parts chitosan fiber, 2-4 parts modified mannan, and 11-14 parts flax fiber.

[0007] Preferably, the hydrophilic inner layer comprises the following raw materials in parts by weight: 25 parts bamboo fiber, 5 parts modified spider silk fiber, 9 parts polylactic acid fiber, 4 parts chitosan fiber, 3 parts modified mannan, and 12.5 parts flax fiber.

[0008] Preferably, the modified spider silk fiber is prepared as follows: spider silk and hexafluoroisopropanol are mixed at a mass ratio of 1:4-6, and 0.1-0.2 times the mass of the spider silk dextran is added. The mixture is stirred to obtain a modified spider silk fiber spinning solution. The modified spider silk fiber spinning solution is electrospun to obtain modified spider silk fiber fibrils. The modified spider silk fiber fibrils are twisted to a linear density of 30-50 dtex, and then treated in a low-temperature plasma generator. The plasma stays on the fiber surface for 2-5 seconds to obtain modified spider silk fiber. By adding dextran and then performing low-temperature plasma treatment, the sweat absorption and breathability of the spider silk fiber are improved, and the modified spider silk fiber has good mechanical properties.

[0009] Preferably, the modified mannan is prepared as follows: glutamic acid, mannan and water are mixed evenly in a mass ratio of 1:8-12:60-80, and the mixture is heated under reflux at 90°C for 1-2 hours. Then, the mixture is concentrated and dried to obtain the modified mannan, which has good sweat absorption, breathability and antibacterial properties.

[0010] Preferably, the preparation of the hydrophilic inner layer yarn includes the following steps: bamboo fiber, polylactic acid fiber, chitosan fiber, and flax fiber are mixed evenly and placed in a sterile culture tank. Then, liquid culture medium and bacterial cellulose fermentation liquid are injected into the culture tank, sealed, and cultured at 25-30℃ for 2-3 days. The culture product is rinsed with deionized water to remove residual culture medium. After soaking in deionized water until colorless, it is filtered and dried for later use. The dried culture product is mixed with modified spider silk fiber and modified mannan and dried. After being processed by roving, spinning, automatic winding, steaming, and high-speed doubling, the yarn is obtained. During the fermentation process, bacterial cellulose grows into the bamboo fiber, polylactic acid fiber, chitosan fiber, and flax fiber, forming an interwoven network with a large storage space, improving sweat absorption and yarn mechanical properties.

[0011] Preferably, the preparation method of the bacterial cellulose fermentation broth is as follows: inoculate Acetobacter xylinum strain into the culture medium, at a temperature of 25-28℃, a stirring speed of 200-240 r / min, and a culture time of 24-36 h to obtain a seed liquid; add 10-15% of the volume of the seed liquid into the culture medium, mix well and set aside to obtain the bacterial cellulose fermentation broth.

[0012] Preferably, the hydrophobic outer layer comprises the following raw materials in parts by weight: 30-40 parts polyurethane, 10-20 parts polyethylene terephthalate, 1-2 parts aziridine crosslinking agent, 1-3 parts modified zein, and 1-3 parts quercetin.

[0013] Preferably, the modified zein is prepared as follows: Zein, fluorinated graphene, and oleic acid are taken in a mass ratio of 10-15:0.4-0.8:1 by weight, and added to an 80-90% ethanol solution (6-10 times the mass of zein). The solution is heated to 40-50°C and stirred for 20-30 minutes. The sediment is separated by centrifugation, dried, and pulverized to obtain the modified zein. By adding fluorinated graphene and oleic acid, the hydrophobicity of the zein is improved, thereby enhancing the waterproof effect of the hydrophobic outer layer.

[0014] The present invention also provides a shirt made of a single-layer absorbent and breathable comfortable fabric manufactured using the above-described manufacturing process.

[0015] Compared with the prior art, the embodiments of this application have the following main advantages: The present invention provides a manufacturing process for a single-layer waterproof and single-layer absorbent comfortable fabric. The fabric comprises a hydrophilic inner layer and a hydrophobic outer layer. By producing hydrophilic inner layer yarn and hydrophobic outer layer yarn, the hydrophilic inner layer and hydrophobic outer layer are respectively made. The skin-contact layer is hydrophilic, quickly absorbs sweat, and evaporates quickly, making it more comfortable to wear. The outer layer is hydrophobic, preventing permeability in the reverse direction, forming a protective barrier, blocking sweat, and eliminating sweat marks. Modified spider silk fiber and modified mannan are added to the hydrophilic inner layer raw material, and the two work synergistically to greatly improve the fabric's moisture absorption and perspiration wicking effect. Modified corn gluten and quercetin are added to the hydrophobic outer layer raw material, and the two work synergistically to greatly improve the fabric's waterproof effect. Attached Figure Description

[0016] Figure 1 This is a flowchart of a manufacturing process for a single-layer absorbent and breathable comfort fabric provided by the present invention. Detailed Implementation

[0017] Unless otherwise defined, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs; the terminology used herein in the specification of the application is for the purpose of describing particular embodiments only and is not intended to be limiting of the application; the terms "comprising" and "having," and any variations thereof, in the specification, claims, and foregoing drawings of this application are intended to cover non-exclusive inclusion. The terms "first," "second," etc., in the specification, claims, or foregoing drawings of this application are used to distinguish different objects, not to describe a particular order.

[0018] In this document, the term "embodiment" means that a particular feature, structure, or characteristic described in connection with an embodiment may be included in at least one embodiment of this application. The appearance of this phrase in various places throughout the specification does not necessarily refer to the same embodiment, nor is it a separate or alternative embodiment mutually exclusive with other embodiments. It will be explicitly and implicitly understood by those skilled in the art that the embodiments described herein can be combined with other embodiments. Example 1

[0019] This invention provides a manufacturing process for a single-layer waterproof and single-layer absorbent comfortable fabric, the fabric comprising a hydrophilic inner layer and a hydrophobic outer layer, such as... Figure 1 As shown, its manufacturing process includes the following steps: To produce a hydrophilic inner layer yarn; To produce a hydrophobic outer layer yarn; The hydrophilic inner layer yarn and the hydrophobic outer layer yarn are woven into a fabric using existing conventional techniques, which will not be described in detail here. Immerse the fabric completely in clean water and rinse twice, each time for 5 minutes. After washing, put the fabric into a spin dryer for 10 minutes to dehydrate it. After dehydration, take it out and lay it flat on a drying rack. The dehydrated fabric is placed in a dyeing vat for dyeing treatment, and then subjected to reduction cleaning. Both the dyeing treatment and reduction cleaning are performed using existing conventional techniques. The shape is set using a setting machine, employing existing conventional technology; The finished fabric is obtained by rolling and packaging the shaped fabric using a rolling machine.

[0020] The hydrophilic inner layer comprises the following raw materials in parts by weight: 20 parts bamboo fiber, 3 parts modified spider silk fiber, 6 parts polylactic acid fiber, 2 parts chitosan fiber, 1 part modified mannan, and 10 parts flax fiber.

[0021] Specifically, the preparation method of the modified spider silk fiber is as follows: Spider silk and hexafluoroisopropanol are mixed at a mass ratio of 1:4, and dextran with a mass ratio of 0.1 times that of the spider silk is added. The mixture is stirred and mixed to obtain a modified spider silk fiber spinning solution. The modified spider silk fiber spinning solution is electrospun to obtain modified spider silk fiber fibrils. The modified spider silk fiber fibrils are twisted to a linear density of 30 dtex, and then treated in a low-temperature plasma generator. The plasma stays on the fiber surface for 2 seconds to obtain modified spider silk fiber.

[0022] In this embodiment, the modified mannan is prepared as follows: glutamic acid, mannan and water are mixed evenly in a mass ratio of 1:8:60, heated and refluxed at 90°C for 1 hour, then concentrated and dried to obtain the modified mannan, which has good sweat absorption, breathability and antibacterial properties.

[0023] In specific implementation, the production of hydrophilic inner layer yarn includes the following steps: bamboo fiber, polylactic acid fiber, chitosan fiber, and flax fiber are mixed evenly and placed in a sterile culture tank. Then, liquid culture medium and bacterial cellulose fermentation broth are injected into the culture tank, sealed, and cultured at 25°C for 2 days. The culture product is rinsed with deionized water to remove residual culture medium. After soaking in deionized water until colorless, it is filtered and dried for later use. The dried culture product is mixed with modified spider silk fiber and modified mannan and dried. After being processed by roving, spinning, automatic winding, steaming, and high-speed doubling, the yarn is obtained.

[0024] The preparation method of the bacterial cellulose fermentation broth is as follows: inoculate Acetobacter xylinum strain into the culture medium, at a temperature of 25℃, a stirring speed of 200r / min, and a culture time of 24h to obtain seed liquid; add 10% of the volume of seed liquid into the culture medium, mix well and set aside to obtain bacterial cellulose fermentation broth.

[0025] In this embodiment, the hydrophobic outer layer comprises the following raw materials in parts by weight: 30 parts polyurethane, 10 parts polyethylene terephthalate, 1 part aziridine crosslinking agent, 1 part modified zein, and 1 part quercetin.

[0026] Specifically, the preparation method of the modified zein is as follows: by weight, zein, fluorinated graphene and oleic acid are taken in a mass ratio of 10:0.4:1, added to an 80% ethanol solution with a mass of 6 times that of zein, heated to 40°C and stirred for 20 minutes, centrifuged to separate the sediment, dried and pulverized to obtain the modified zein. Example 2

[0027] This invention provides a manufacturing process for a single-layer waterproof and single-layer absorbent comfortable fabric, the fabric comprising a hydrophilic inner layer and a hydrophobic outer layer, such as... Figure 1 As shown, its manufacturing process includes the following steps: To produce a hydrophilic inner layer yarn; To produce a hydrophobic outer layer yarn; The hydrophilic inner layer yarn and the hydrophobic outer layer yarn are woven into a fabric using existing conventional techniques, which will not be described in detail here. Immerse the fabric completely in clean water and rinse twice, each time for 5 minutes. After washing, put the fabric into a spin dryer for 10 minutes to dehydrate it. After dehydration, take it out and lay it flat on a drying rack. The dehydrated fabric is placed in a dyeing vat for dyeing treatment, and then subjected to reduction cleaning. Both the dyeing treatment and reduction cleaning are performed using existing conventional techniques. The shape is set using a setting machine, employing existing conventional technology; The finished fabric is obtained by rolling and packaging the shaped fabric using a rolling machine.

[0028] The hydrophilic inner layer comprises the following raw materials in parts by weight: 23 parts bamboo fiber, 4 parts modified spider silk fiber, 8 parts polylactic acid fiber, 3 parts chitosan fiber, 2 parts modified mannan, and 11 parts flax fiber.

[0029] Specifically, the preparation method of the modified spider silk fiber is as follows: Spider silk and hexafluoroisopropanol are mixed at a mass ratio of 1:4, and dextran with a mass ratio of 0.1 times that of the spider silk is added. The mixture is stirred and mixed to obtain a modified spider silk fiber spinning solution. The modified spider silk fiber spinning solution is electrospun to obtain modified spider silk fiber fibrils. The modified spider silk fiber fibrils are twisted to a linear density of 30 dtex, and then treated in a low-temperature plasma generator. The plasma stays on the fiber surface for 2 seconds to obtain modified spider silk fiber.

[0030] In this embodiment, the modified mannan is prepared as follows: glutamic acid, mannan and water are mixed evenly in a mass ratio of 1:8:60, heated and refluxed at 90°C for 1 hour, then concentrated and dried to obtain the modified mannan, which has good sweat absorption, breathability and antibacterial properties.

[0031] In specific implementation, the production of hydrophilic inner layer yarn includes the following steps: bamboo fiber, polylactic acid fiber, chitosan fiber, and flax fiber are mixed evenly and placed in a sterile culture tank. Then, liquid culture medium and bacterial cellulose fermentation broth are injected into the culture tank, sealed, and cultured at 25°C for 2 days. The culture product is rinsed with deionized water to remove residual culture medium. After soaking in deionized water until colorless, it is filtered and dried for later use. The dried culture product is mixed with modified spider silk fiber and modified mannan and dried. After being processed by roving, spinning, automatic winding, steaming, and high-speed doubling, the yarn is obtained.

[0032] The preparation method of the bacterial cellulose fermentation broth is as follows: inoculate Acetobacter xylinum strain into the culture medium, at a temperature of 25℃, a stirring speed of 200r / min, and a culture time of 24h to obtain seed liquid; add 10% of the volume of seed liquid into the culture medium, mix well and set aside to obtain bacterial cellulose fermentation broth.

[0033] In this embodiment, the hydrophobic outer layer comprises the following raw materials in parts by weight: 30 parts polyurethane, 10 parts polyethylene terephthalate, 1 part aziridine crosslinking agent, 1 part modified zein, and 1 part quercetin.

[0034] Specifically, the preparation method of the modified zein is as follows: by weight, zein, fluorinated graphene and oleic acid are taken in a mass ratio of 10:0.4:1, added to an 80% ethanol solution with a mass of 6 times that of zein, heated to 40°C and stirred for 20 minutes, centrifuged to separate the sediment, dried and pulverized to obtain the modified zein. Example 3

[0035] This invention provides a manufacturing process for a single-layer waterproof and single-layer absorbent comfortable fabric, the fabric comprising a hydrophilic inner layer and a hydrophobic outer layer, such as... Figure 1 As shown, its manufacturing process includes the following steps: To produce a hydrophilic inner layer yarn; To produce a hydrophobic outer layer yarn; The hydrophilic inner layer yarn and the hydrophobic outer layer yarn are woven into a fabric using existing conventional techniques, which will not be described in detail here. Immerse the fabric completely in clean water and rinse twice, each time for 5 minutes. After washing, put the fabric into a spin dryer for 10 minutes to dehydrate it. After dehydration, take it out and lay it flat on a drying rack. The dehydrated fabric is placed in a dyeing vat for dyeing treatment, and then subjected to reduction cleaning. Both the dyeing treatment and reduction cleaning are performed using existing conventional techniques. The shape is set using a setting machine, employing existing conventional technology; The finished fabric is obtained by rolling and packaging the shaped fabric using a rolling machine.

[0036] The hydrophilic inner layer comprises the following raw materials in parts by weight: 25 parts bamboo fiber, 5 parts modified spider silk fiber, 9 parts polylactic acid fiber, 4 parts chitosan fiber, 3 parts modified mannan, and 12.5 parts flax fiber.

[0037] Specifically, the preparation method of the modified spider silk fiber is as follows: Spider silk and hexafluoroisopropanol are mixed at a mass ratio of 1:5, and dextran with a mass of 0.15 times that of the spider silk is added. The mixture is stirred and mixed to obtain a modified spider silk fiber spinning solution. The modified spider silk fiber spinning solution is electrospun to obtain modified spider silk fiber fibrils. The modified spider silk fiber fibrils are twisted to a linear density of 40 dtex, and then treated in a low-temperature plasma generator. The plasma stays on the fiber surface for 3 seconds to obtain modified spider silk fiber.

[0038] In this embodiment, the modified mannan is prepared as follows: glutamic acid, mannan and water are mixed evenly in a mass ratio of 1:10:70, heated and refluxed at 90°C for 1.5 hours, then concentrated and dried to obtain the modified mannan, which has good sweat absorption, breathability and antibacterial properties.

[0039] In specific implementation, the production of hydrophilic inner layer yarn includes the following steps: bamboo fiber, polylactic acid fiber, chitosan fiber, and flax fiber are mixed evenly and placed in a sterile culture tank. Then, liquid culture medium and bacterial cellulose fermentation broth are injected into the culture tank, sealed, and cultured at 28°C for 2 days. The culture product is rinsed with deionized water to remove residual culture medium. After soaking in deionized water until colorless, it is filtered and dried for later use. The dried culture product is mixed with modified spider silk fiber and modified mannan and dried. After being processed by roving, spinning, automatic winding, steaming, and high-speed doubling, the yarn is obtained.

[0040] The preparation method of the bacterial cellulose fermentation broth is as follows: inoculate Acetobacter xylinum strain into the culture medium, at a temperature of 25℃, a stirring speed of 220r / min, and a culture time of 30h to obtain seed liquid; add 10% of the volume of seed liquid into the culture medium, mix well and set aside to obtain bacterial cellulose fermentation broth.

[0041] In this embodiment, the hydrophobic outer layer comprises the following raw materials in parts by weight: 30-40 parts polyurethane, 15 parts polyethylene terephthalate, 1.5 parts aziridine crosslinking agent, 2 parts modified zein, and 2 parts quercetin.

[0042] Specifically, the preparation method of the modified zein is as follows: by weight, zein, fluorinated graphene and oleic acid are taken in a mass ratio of 12.5:0.6:1, added to an 85% ethanol solution with a mass of 8 times that of zein, heated to 45°C and stirred for 25 minutes, centrifuged to separate the sediment, dried and pulverized to obtain the modified zein. Example 4

[0043] This invention provides a manufacturing process for a single-layer waterproof and single-layer absorbent comfortable fabric, the fabric comprising a hydrophilic inner layer and a hydrophobic outer layer, such as... Figure 1 As shown, its manufacturing process includes the following steps: To produce a hydrophilic inner layer yarn; To produce a hydrophobic outer layer yarn; The hydrophilic inner layer yarn and the hydrophobic outer layer yarn are woven into a fabric using existing conventional techniques, which will not be described in detail here. Immerse the fabric completely in clean water and rinse twice, each time for 5 minutes. After washing, put the fabric into a spin dryer for 10 minutes to dehydrate it. After dehydration, take it out and lay it flat on a drying rack. The dehydrated fabric is placed in a dyeing vat for dyeing treatment, and then subjected to reduction cleaning. Both the dyeing treatment and reduction cleaning are performed using existing conventional techniques. The shape is set using a setting machine, employing existing conventional technology; The finished fabric is obtained by rolling and packaging the shaped fabric using a rolling machine.

[0044] The hydrophilic inner layer comprises the following raw materials in parts by weight: 27 parts bamboo fiber, 6 parts modified spider silk fiber, 10 parts polylactic acid fiber, 5 parts chitosan fiber, 4 parts modified mannan, and 14 parts flax fiber.

[0045] Specifically, the preparation method of the modified spider silk fiber is as follows: Spider silk and hexafluoroisopropanol are mixed at a mass ratio of 1:6, and dextran of 0.2 times the mass of spider silk is added. The mixture is stirred to obtain a modified spider silk fiber spinning solution. The modified spider silk fiber spinning solution is electrospun to obtain modified spider silk fiber fibrils. The modified spider silk fiber fibrils are twisted to a linear density of 50 dtex, and then treated in a low-temperature plasma generator. The plasma stays on the fiber surface for 5 seconds to obtain modified spider silk fiber.

[0046] In this embodiment, the modified mannan is prepared as follows: glutamic acid, mannan and water are mixed evenly in a mass ratio of 1:12:80, heated and refluxed at 90°C for 2 hours, then concentrated and dried to obtain the modified mannan, which has good sweat absorption, breathability and antibacterial properties.

[0047] In specific implementation, the production of hydrophilic inner layer yarn includes the following steps: bamboo fiber, polylactic acid fiber, chitosan fiber, and flax fiber are mixed evenly and placed in a sterile culture tank. Then, liquid culture medium and bacterial cellulose fermentation broth are injected into the culture tank, sealed, and cultured at 30°C for 3 days. The culture product is rinsed with deionized water to remove residual culture medium. After soaking in deionized water until colorless, it is filtered and dried for later use. The dried culture product is mixed with modified spider silk fiber and modified mannan and dried. After being processed by roving, spinning, automatic winding, steaming, and high-speed doubling, the yarn is obtained.

[0048] The preparation method of the bacterial cellulose fermentation broth is as follows: inoculate Acetobacter xylinum strain into the culture medium, at a temperature of 28℃, a stirring speed of 240r / min, and a culture time of 36h to obtain seed liquid; add 15% of the volume of seed liquid into the culture medium, mix well and set aside to obtain bacterial cellulose fermentation broth.

[0049] In this embodiment, the hydrophobic outer layer comprises the following raw materials in parts by weight: 40 parts polyurethane, 20 parts polyethylene terephthalate, 2 parts aziridine crosslinking agent, 3 parts modified zein, and 3 parts quercetin.

[0050] Specifically, the preparation method of the modified zein is as follows: by weight, take zein, fluorinated graphene and oleic acid in a mass ratio of 15:0.8:1, add them to a 90% ethanol solution with a mass of 10 times that of zein, heat to 50°C and stir for 30 minutes, centrifuge to separate the sediment, dry and pulverize to obtain the modified zein. Example 5

[0051] This invention provides a manufacturing process for a single-layer waterproof and single-layer absorbent comfortable fabric, the fabric comprising a hydrophilic inner layer and a hydrophobic outer layer, such as... Figure 1 As shown, its manufacturing process includes the following steps: To produce a hydrophilic inner layer yarn; To produce a hydrophobic outer layer yarn; The hydrophilic inner layer yarn and the hydrophobic outer layer yarn are woven into a fabric using existing conventional techniques, which will not be described in detail here. Immerse the fabric completely in clean water and rinse twice, each time for 5 minutes. After washing, put the fabric into a spin dryer for 10 minutes to dehydrate it. After dehydration, take it out and lay it flat on a drying rack. The dehydrated fabric is placed in a dyeing vat for dyeing treatment, and then subjected to reduction cleaning. Both the dyeing treatment and reduction cleaning are performed using existing conventional techniques. The shape is set using a setting machine, employing existing conventional technology; The finished fabric is obtained by rolling and packaging the shaped fabric using a rolling machine.

[0052] The hydrophilic inner layer comprises the following raw materials in parts by weight: 30 parts bamboo fiber, 7 parts modified spider silk fiber, 12 parts polylactic acid fiber, 6 parts chitosan fiber, 5 parts modified mannan, and 15 parts flax fiber.

[0053] Specifically, the preparation method of the modified spider silk fiber is as follows: Spider silk and hexafluoroisopropanol are mixed at a mass ratio of 1:6, and dextran of 0.2 times the mass of spider silk is added. The mixture is stirred to obtain a modified spider silk fiber spinning solution. The modified spider silk fiber spinning solution is electrospun to obtain modified spider silk fiber fibrils. The modified spider silk fiber fibrils are twisted to a linear density of 50 dtex, and then treated in a low-temperature plasma generator. The plasma stays on the fiber surface for 5 seconds to obtain modified spider silk fiber.

[0054] In this embodiment, the modified mannan is prepared as follows: glutamic acid, mannan and water are mixed evenly in a mass ratio of 1:12:80, heated and refluxed at 90°C for 2 hours, then concentrated and dried to obtain the modified mannan, which has good sweat absorption, breathability and antibacterial properties.

[0055] In specific implementation, the production of hydrophilic inner layer yarn includes the following steps: bamboo fiber, polylactic acid fiber, chitosan fiber, and flax fiber are mixed evenly and placed in a sterile culture tank. Then, liquid culture medium and bacterial cellulose fermentation broth are injected into the culture tank, sealed, and cultured at 30°C for 3 days. The culture product is rinsed with deionized water to remove residual culture medium. After soaking in deionized water until colorless, it is filtered and dried for later use. The dried culture product is mixed with modified spider silk fiber and modified mannan and dried. After being processed by roving, spinning, automatic winding, steaming, and high-speed doubling, the yarn is obtained.

[0056] The preparation method of the bacterial cellulose fermentation broth is as follows: inoculate Acetobacter xylinum strain into the culture medium, at a temperature of 28℃, a stirring speed of 240r / min, and a culture time of 36h to obtain seed liquid; add 15% of the volume of seed liquid into the culture medium, mix well and set aside to obtain bacterial cellulose fermentation broth.

[0057] In this embodiment, the hydrophobic outer layer comprises the following raw materials in parts by weight: 40 parts polyurethane, 20 parts polyethylene terephthalate, 2 parts aziridine crosslinking agent, 3 parts modified zein, and 3 parts quercetin.

[0058] Specifically, the preparation method of the modified zein is as follows: by weight, take zein, fluorinated graphene and oleic acid in a mass ratio of 15:0.8:1, add them to a 90% ethanol solution with a mass of 10 times that of zein, heat to 50°C and stir for 30 minutes, centrifuge to separate the sediment, dry and pulverize to obtain the modified zein.

[0059] Comparative Example 1: The difference from Example 3 is that the modified spider silk fiber of the hydrophilic inner layer is replaced with ordinary spider silk fiber.

[0060] Comparative Example 2: The difference from Example 3 is that the modified mannan raw material for the hydrophilic inner layer was replaced with ordinary mannan.

[0061] Comparative Example 3: The difference from Example 3 is that the modified spider silk fiber of the hydrophilic inner layer was replaced with ordinary spider silk fiber and the modified mannan of the hydrophilic inner layer was replaced with ordinary mannan.

[0062] Comparative Example 4: The difference from Example 3 is that the modified zein for the hydrophobic outer layer was replaced with ordinary zein.

[0063] Comparative Example 5: The difference from Example 3 is that the raw material of the hydrophobic outer layer does not contain quercetin.

[0064] Comparative Example 6: The difference from Example 3 is that the modified zein for the hydrophobic outer layer is replaced with ordinary zein and does not contain quercetin.

[0065] I. The water droplet diffusion time of the hydrophilic inner layer of the fabric was tested according to GB / T 21655.1-2008 "Evaluation of the moisture absorption and quick-drying properties of textiles". The test results are shown in Table 1 below: Example 1 2.3 Example 2 2.1 Example 3 2.0 Example 4 2.1 Example 5 2.2 Comparative Example 1 5.2 Comparative Example 2 5.8 Comparative Example 3 7.8 The results above show that the present invention provides a single-layer waterproof and absorbent comfortable fabric with a hydrophilic inner layer that has good sweat-wicking and moisture-wicking functions. In particular, by adding modified spider silk fibers and modified mannan, the two work synergistically to greatly improve the fabric's moisture-wicking and sweat-wicking effect.

[0066] 2. The hydrophobic contact angle of the outer layer of the fabric in Examples 1-5 and Comparative Examples 1-3 was measured (the contact angle measuring instrument was a DSA25E contact angle measuring instrument from Kruss GmbH, Germany). The test results are shown in Table 2 below: Example 1 143.9±2.2 Example 2 144.1±2.6 Example 3 145.5±2.4 Example 4 145.1±2.5 Example 5 144.6±2.0 Comparative Example 1 124.3±2.3 Comparative Example 2 122.5±2.4 Comparative Example 3 110.8±2.1 The results above show that the present invention provides a single-layer waterproof and absorbent comfortable fabric with a hydrophobic outer layer that has good waterproof function. In particular, by adding modified corn gluten and quercetin, the two work synergistically to greatly improve the waterproof effect of the fabric.

[0067] It should be noted that, for the sake of simplicity, the foregoing embodiments are all described as a series of actions. However, those skilled in the art should understand that the present invention is not limited to the described order of actions, as some steps may be performed in other orders or simultaneously according to the present invention. Furthermore, those skilled in the art should also understand that the embodiments described in the specification are preferred embodiments, and the actions and modules involved are not necessarily essential to the present invention.

[0068] The above embodiments are only used to illustrate the technical solutions of the present invention, and are not intended to limit the scope of protection of the invention. Obviously, the described embodiments are only some embodiments of the present invention, not all embodiments. Based on these embodiments, all other embodiments obtained by those skilled in the art without creative effort are within the scope of protection of the present invention. Although the present invention has been described in detail with reference to the above embodiments, those skilled in the art can still combine, add, delete, or otherwise adjust the features of the various embodiments of the present invention according to the circumstances without conflict or creative effort, thereby obtaining different technical solutions that do not fundamentally depart from the concept of the present invention. These technical solutions also fall within the scope of protection of the present invention.

Claims

1. A manufacturing process for a single-layer absorbent and breathable comfortable fabric, characterized in that, The fabric comprises a hydrophilic inner layer and a hydrophobic outer layer, and the manufacturing process includes the following steps: To produce a hydrophilic inner layer yarn; To produce a hydrophobic outer layer yarn; Weave the hydrophilic inner layer yarn and the hydrophobic outer layer yarn into a fabric; Completely immerse the fabric in clean water and rinse it 2-3 times, each rinsing time being 5-10 minutes. After washing, put the fabric into a spin dryer for 10-20 minutes to dehydrate it. After dehydration, take it out and lay it flat on a drying rack. The dehydrated fabric is placed in a dye vat for dyeing, and then washed to restore its original state. The shape is set using a setting machine; The finished fabric is obtained by rolling and packaging the shaped fabric using a rolling machine; The hydrophilic inner layer comprises the following raw materials in parts by weight: 20-30 parts bamboo fiber, 3-7 parts modified spider silk fiber, 6-12 parts polylactic acid fiber, 2-6 parts chitosan fiber, 1-5 parts modified mannan, and 10-15 parts flax fiber. The modified spider silk fiber is prepared as follows: Spider silk and hexafluoroisopropanol are mixed at a mass ratio of 1:4-6, and 0.1-0.2 times the mass of spider silk dextran is added. The mixture is stirred to obtain a modified spider silk fiber spinning solution. The modified spider silk fiber spinning solution is electrospun to obtain modified spider silk fiber fibrils. The modified spider silk fiber fibrils are twisted to a linear density of 30-50 dtex, and then treated in a low-temperature plasma generator. The plasma stays on the fiber surface for 2-5 seconds to obtain modified spider silk fiber. The modified mannan is prepared as follows: glutamic acid, mannan and water are mixed evenly in a mass ratio of 1:8-12:60-80, and the mixture is heated under reflux at 90°C for 1-2 hours. Then the mixture is concentrated and dried to obtain the modified mannan. The process of producing hydrophilic inner layer yarn includes the following steps: bamboo fiber, polylactic acid fiber, chitosan fiber, and flax fiber are mixed evenly and placed in a sterile culture tank. Then, liquid culture medium and bacterial cellulose fermentation broth are injected into the culture tank, sealed, and cultured at 25-30℃ for 2-3 days. The culture product is rinsed with deionized water to remove residual culture medium. After soaking in deionized water until colorless, it is filtered and dried for later use. The dried culture product is mixed with modified spider silk fiber and modified mannan and dried. After processing through roving, spinning, automatic winding, steaming, and high-speed doubling, the yarn is obtained.

2. The manufacturing process of the single-layer absorbent and single-layer protective comfortable fabric as described in claim 1, characterized in that, The hydrophilic inner layer comprises the following raw materials in parts by weight: 23-27 parts bamboo fiber, 4-6 parts modified spider silk fiber, 8-10 parts polylactic acid fiber, 3-5 parts chitosan fiber, 2-4 parts modified mannan, and 11-14 parts flax fiber.

3. The manufacturing process of the single-layer absorbent and single-layer protective comfortable fabric as described in claim 2, characterized in that, The hydrophilic inner layer comprises the following raw materials in parts by weight: 25 parts bamboo fiber, 5 parts modified spider silk fiber, 9 parts polylactic acid fiber, 4 parts chitosan fiber, 3 parts modified mannan, and 12.5 parts flax fiber.

4. The manufacturing process of the single-layer absorbent and single-layer protective comfortable fabric as described in claim 1, characterized in that, The preparation method of the bacterial cellulose fermentation broth is as follows: inoculate Acetobacter xylinum into the culture medium, maintain the temperature at 25-28℃, stir at 200-240 r / min, and culture for 24-36 h to obtain the seed broth; Inoculate the culture medium with 10-15% of the seed culture, mix well and set aside to obtain bacterial cellulose fermentation broth.

5. The manufacturing process of the single-layer absorbent and single-layer protective comfortable fabric as described in claim 1, characterized in that, The hydrophobic outer layer comprises the following raw materials in parts by weight: 30-40 parts polyurethane, 10-20 parts polyethylene terephthalate, 1-2 parts aziridine crosslinking agent, 1-3 parts modified zein, and 1-3 parts quercetin.

6. The manufacturing process of the single-layer absorbent and single-layer protective comfortable fabric as described in claim 5, characterized in that, The modified zein is prepared as follows: zein, fluorinated graphene, and oleic acid are taken in a mass ratio of 10-15:0.4-0.8:1 by weight. These are added to an 80-90% ethanol solution, which is 6-10 times the mass of the zein. The solution is heated to 40-50℃ and stirred for 20-30 minutes. The sediment is then separated by centrifugation, dried, and pulverized to obtain the modified zein.

Citation Information

Patent Citations

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    CN111826773A