一种基于调幅分解的氧化铝复合陶瓷材料及其制备方法

By introducing zirconium oxide, hafnium oxide, and titanium oxide into alumina composites and using a modulated decomposition process with carbon powder, a nanoscale layered structure is formed, solving the problem of balancing hardness and toughness in alumina composites. This results in a significant improvement in material properties and has broad prospects for industrial applications.

CN118619656BActive Publication Date: 2026-07-17SHANDONG UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHANDONG UNIV
Filing Date
2024-05-30
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing alumina composite materials cannot simultaneously achieve high hardness and high toughness. Current technologies often sacrifice one aspect of performance to compensate for other properties during the reinforcement process.

Method used

By mixing zirconium oxide or hafnium oxide, titanium oxide and carbon powder and sintering them under a protective atmosphere to form complex carbides, then mixing them with alumina and performing rapid hot pressing sintering, followed by aging treatment at specific temperatures and times, amplitude modulation decomposition is initiated to form a nanoscale layered structure, thereby improving the hardness and toughness of the material.

Benefits of technology

Alumina composite ceramic materials with excellent comprehensive performance were prepared, with significantly improved hardness and toughness. The process is simple and easy to implement, with a wide range of applications and high potential for industrial application.

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Abstract

本发明公开了一种基于调幅分解的氧化铝复合陶瓷材料及其制备方法,属于氧化铝陶瓷材料制备领域。本发明通过将氧化物粉末和石墨粉混合后进行无压烧结快速制备出大量的未发生调幅分解的复式碳化物材料;将复式碳化物材料与氧化铝和少量烧结助剂充分混合后快速热压烧结,制得到致密的复式碳化物增强氧化铝基陶瓷材料;再将该种陶瓷材料在特定的温度和时间下进行时效处理,材料内部出现调幅分解现象,使其硬度和韧性协同提升,得到高强度和高韧性的氧化铝复合陶瓷材料。本发明的制备方法具有简单易行、成本低且适用范围广的特点,所制备出的粉料经过时效处理后出现调幅分解现象,其硬度和韧性提升显著。
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