一种低成本高硬度粉末涂料用聚酯树脂及其制备方法

By preparing a low-acid-value, high-functionality polyester resin and combining it with PT910 curing agent, the problems of poor storage stability and low hardness of the PT910 curing agent system were solved, realizing a low-cost, high-hardness powder coating with good storage stability and film hardness. This reduced the cost of powder coatings and utilized HAA byproducts, providing a high-value-added utilization pathway.

CN118725700BActive Publication Date: 2026-07-17ANHUI HENGLONG NEW MATERIALS CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
ANHUI HENGLONG NEW MATERIALS CO LTD
Filing Date
2024-07-24
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing PT910 curing agent system powder coatings suffer from poor storage stability, low hardness, and high cost, making it difficult to develop low-cost, high-hardness powder coatings.

Method used

A low-acid-value, high-functionality polyester resin was prepared by transesterification and polymerization using raw materials such as 2-methyl-2-propyl-1,3-propanediol, ethylene glycol, HAA byproducts, terephthalic acid, trimellitic acid, 2-ethyl-1,3-hexanediol, and 2,3-naphthalenedicarboxylic anhydride. This resin was then formulated with PT910 curing agent to form a low-cost, high-hardness powder coating.

Benefits of technology

It achieves low-cost, high-hardness powder coatings with good storage stability and a film hardness of 3H or higher, exhibiting excellent overall performance. It reduces the amount of PT910 curing agent used, thereby lowering the cost of powder coatings, and utilizes HAA byproducts, providing a high-value-added utilization pathway.

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Abstract

本发明涉及一种低成本高硬度粉末涂料用聚酯树脂,其主要使用2‑甲基‑2‑丙基‑1,3‑丙二醇、乙二醇、HAA副产品、对苯二甲酸、偏苯三甲酸、2‑乙基‑1,3‑己二醇、2,3‑萘二甲酸酐等作为原料来进行聚合得到,最终可以得到官能度较高的低酸值聚酯树脂。该低酸值高官能度的聚酯树脂与官能度较低的PT910固化剂搭配制备的粉末涂料,具有PT910固化剂用量少、粉末涂料成本低的优点,而且储存稳定性好,经过充分固化后,涂膜的硬度基本都在3H,综合性能较优。同时由于综合利用了HAA副产品,不仅聚酯树脂的原料成本低,也为HAA副产品的高附加值利用提供了途径。
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