一种钛基磷酸盐活性材料及其制备方法与应用

By using solid-state reaction high-temperature sintering and reagent treatment, the problem of impurities in industrial pure raw materials affecting the battery performance of titanium-based phosphate materials was solved, realizing the preparation of efficient and low-cost titanium-based phosphate active materials suitable for sodium-ion batteries.

CN118754076BActive Publication Date: 2026-07-17BENAN ENERGY TECH JIANGSU CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
BENAN ENERGY TECH JIANGSU CO LTD
Filing Date
2024-06-07
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies make it difficult to effectively synthesize titanium-based phosphate materials using industrially pure raw materials. Impurities affect battery performance, resulting in high costs and difficulty in industrial production.

Method used

A solid-state reaction high-temperature sintering method was adopted, using sodium hydroxide or ammonia water and reagents such as barium carbonate, barium chloride, and calcium chloride to treat industrial-grade raw materials. The particle size was reduced by air jet milling and wet grinding, combined with spray drying and inert atmosphere sintering, to prepare structurally stable titanium-based phosphate active materials.

Benefits of technology

It lowers the purity requirements for raw materials, improves the purity of material synthesis, enhances battery performance, reduces manufacturing costs, and is suitable for industrial production.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明公开了一种钛基磷酸盐活性材料及其制备方法与应用,属于电池材料制备技术领域。电池正极材料NaaTibXc的制备方法为:将钠源、磷源和有机碳源溶于水中,与分散剂混合,随后加入试剂一和试剂二反应,反应结束后收集溶液部分,加入无机碳源和钛源,湿法研磨,喷雾干燥得到前驱体粉末,烧结并降低粒径得到所述活性材料。本发明采用低品质的工业纯原材料为基础,并根据原材料特征选取处理试剂的组合,设计了一种制备方法用于满足钛基磷酸盐作为钠离子电池材料的电化学性能。本发明方法可以大大降低制备成本,是一种简单易行、绿色低成本、高效能且易于工业化生产的制备方式,具有广阔的商业价值。
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