A TPE micro-foamed mouse and keyboard wrist pad material

Abstract

The present invention relates to a TPE micro-foamed mouse and keyboard wrist pad material, wherein the components are calculated by weight and include: 55-75 parts of hydrogenated styrene-butadiene block copolymer, 8-16 parts of ethylene-octene copolymer, 5-10 parts of ethylene-vinyl acetate copolymer, 6-12 parts of modified filler, 2.5-7.5 parts of masterbatch, 3-8 parts of lubricant, 1.1-1.7 parts of foaming agent and 0.2-1 parts of antioxidant. The present invention prepares a TPE micro-foamed material, which has good strength and resilience, can be used for a wrist pad of a mouse and keyboard, has good enhancement of the effective support of the wrist, and can also have good heat resistance and aging resistance, thereby enhancing its application in a relatively high temperature environment.

Description

Technical Field

[0001] The invention relates to the field of thermoplastic elastomers, and in particular to a TPE micro-foamed mouse and keyboard wrist pad material. Background Art

[0002] TPE (Thermoplastic Elastomer) is a thermoplastic elastomer material with high strength, high resilience, injection molding processability, wide application range, environmental protection, non-toxicity, safety, and excellent colorability. TPE material is soft to the touch, does not require vulcanization, can be recycled to reduce costs, can be secondary injection molding, coated with PP, PE, PC, PS, ABS and other base materials, or can be molded alone.

[0003] Traditionally, when using a mouse and keyboard, the wrist is basically unprotected. When the user operates the mouse and keyboard for a long time, the user's wrist will often feel tired very easily, which is very detrimental to the user's health. The existing wrist guard materials or sponge wrist pads have the defects of large deformation and inability to provide effective support, which still cannot solve the problem of wrist fatigue caused by long-term computer use. The wrist pad made of TPE material can remain soft and comfortable when using the computer, and the effective support for the wrist is also greatly improved, thereby effectively relieving wrist and shoulder fatigue. However, as people's requirements increase, the defects of existing TPE materials have gradually emerged, such as poor heat resistance, poor compression rebound, poor aging resistance, etc. Therefore, it is more important to have a TPE wrist pad material that is resistant to high temperatures, has high resilience and good aging resistance. Summary of the invention

[0004] In view of the problems existing in the prior art, the purpose of the present invention is to provide a TPE micro-foamed mouse and keyboard wrist pad material.

[0005] The purpose of the present invention is achieved by the following technical solutions:

[0006] A TPE micro-foamed mouse and keyboard wrist pad material, the components of which are calculated by weight and include:

[0007] 55-75 parts of hydrogenated styrene-butadiene block copolymer, 8-16 parts of ethylene-octene copolymer, 5-10 parts of ethylene-vinyl acetate copolymer, 6-12 parts of modified filler, 2.5-7.5 parts of masterbatch, 3-8 parts of lubricant, 1.1-1.7 parts of foaming agent and 0.2-1 parts of antioxidant.

[0008] Preferably, the brand of the hydrogenated styrene-butadiene block copolymer is one or more combinations of SEBS YH-501T, SEBS YH-502T, SEBS YH-503T, SEBS YH-506T, SEBS YH-602T and SEBS YH-688.

[0009] Preferably, the grade of the ethylene-octene copolymer is one or more combinations of POE 8770, POE 8137, POE 8407 and POE 8440.

[0010] Preferably, the grade of the ethylene-vinyl acetate copolymer is one or more combinations of EVA 625, EVA 630, EVA 510 and EVA541.

[0011] Preferably, the brand of the masterbatch is one of PLASBLAK UN6073, PLASBLAK UN2005 and PLASBLAK G3807.

[0012] Preferably, the lubricant is a mixture of one or more of zinc stearate, magnesium stearate, calcium stearate and stearic acid.

[0013] Preferably, the foaming agent is one of 4,4-oxobisbenzenesulfonyl hydrazide, azodicarbonamide, and dinitrosopentamethylenetetramine.

[0014] Preferably, the antioxidant is a mixture of one or more of antioxidant 4010, antioxidant 2246, and antioxidant 1076.

[0015] Preferably, the preparation method of the modified filler comprises:

[0016] S1. Mix tungsten silicide and hydrogen peroxide solution, ultrasonically treat for 1-3 hours, centrifuge, wash and dry to obtain activated tungsten silicide; mix activated tungsten silicide and anhydrous ethanol, add vinyltrimethoxysilane, reflux and stir for 4-6 hours, and after the treatment, centrifuge, wash and dry to obtain vinyl-modified tungsten silicide;

[0017] S2, 2-vinylbenzaldehyde and 3-amino-1,2,4-triazole are mixed in toluene, nitrogen is used as a protective gas, the temperature is gradually raised to 100-115°C, and refluxed and stirred for 3-6 hours under the action of glacial acetic acid. After the reaction is completed, the solvent is removed under pressure to obtain a vinyl intermediate product;

[0018] S3. The vinyl-modified tungsten silicide and the vinyl intermediate product are mixed in tetrahydrofuran, nitrogen is used as a protective gas, an initiator azobisisobutyronitrile is added, the temperature is raised to 60-80° C., the mixture is stirred for 8-16 hours, and then centrifuged, washed and dried to obtain a modified filler.

[0019] Preferably, in S1, the particle size of tungsten silicide is 80-120 μm, and the mass fraction of hydrogen peroxide solution is 20%-30%.

[0020] Preferably, in S1, the mass ratio of tungsten silicide to hydrogen peroxide solution is 1:15-20.

[0021] Preferably, in S1, the mass ratio of activated tungsten silicide, vinyltrimethoxysilane and anhydrous ethanol is 1:0.2-0.4:10-20.

[0022] Preferably, in S2, the mass ratio of 2-vinylbenzaldehyde, 3-amino-1,2,4-triazole and toluene is 1.3-2.6:1.1-2.2:15-25.

[0023] Preferably, in S2, the amount of glacial acetic acid added is 2%-6% of the mass of 2-vinylbenzaldehyde.

[0024] Preferably, in S3, the mass ratio of vinyl-modified tungsten silicide, vinyl intermediate product and tetrahydrofuran is 1:1.2-1.8:10-20.

[0025] Preferably, in S3, the amount of the initiator azobisisobutyronitrile added is 3%-8% of the mass of the vinyl intermediate product.

[0026] Preferably, the preparation method of the TPE micro-foamed mouse and keyboard wrist pad material comprises the following steps:

[0027] Step 1, weighing hydrogenated styrene-butadiene block copolymer, ethylene-octene copolymer, ethylene-vinyl acetate copolymer, modified filler, masterbatch, lubricant and antioxidant according to weight parts, and mixing them in a mixer at a mixing temperature of 100-120° C. for 10-20 min;

[0028] Step 2, adding a foaming agent to the mixture of step 1, continuing to maintain the temperature and kneading for 5-10 minutes, then pouring it into an extruder, and performing extrusion foaming molding at 150-180° C. to obtain a TPE micro-foamed mouse and keyboard wrist pad material.

[0029] The beneficial effects of the present invention are:

[0030] 1. The present invention prepares a TPE micro-foam material with good strength and resilience, which can be used for wrist pads of mice and keyboards. While effectively enhancing the support for the wrist, it also has good heat resistance and aging resistance, thereby enhancing its application in relatively high temperature environments.

[0031] 2. The TPE micro-foam material prepared by the present invention uses hydrogenated styrene-butadiene block copolymer (SEBS) as the main raw material, ethylene-octene copolymer (POE) and ethylene-vinyl acetate copolymer (EVA) as auxiliary raw materials, modified filler as the main filler, masterbatch as the coloring agent, and also adds lubricant, foaming agent and antioxidant as auxiliary agents.

[0032] 3. Compared with traditional inorganic fillers, the modified filler used in the present invention not only has stronger crosslinking with the raw materials, but also can enhance the performance of the raw materials, such as strength, compression resilience, heat resistance and aging resistance. The modified filler of the present invention is prepared by crosslinking polymerization of a vinyl intermediate product generated by the reaction of 2-vinylbenzaldehyde and 3-amino-1,2,4-triazole and vinyl-modified tungsten silicide.

[0033] 4. In the preparation process of modified fillers, 2-vinylbenzaldehyde containing aldehyde and vinyl groups reacts with 3-amino-1,2,4-triazole containing amino and triazole groups through amine-aldehyde condensation reaction to form an intermediate product containing vinyl, Schiff base and triazole groups; then it is cross-linked with vinyl-modified tungsten silicide through vinyl polymerization to form an organic-inorganic coated material for use as a filler. DETAILED DESCRIPTION

[0034] The technical solution of the present invention is described below through specific examples. It should be understood that the one or more method steps mentioned in the present invention do not exclude the existence of other method steps before and after the combination step or the insertion of other method steps between these explicitly mentioned steps; it should also be understood that these embodiments are only used to illustrate the present invention and are not used to limit the scope of the present invention. Moreover, unless otherwise specified, the numbering of each method step is only a convenient tool for identifying each method step, and is not intended to limit the order of arrangement of each method step or to limit the scope of the present invention. The change or adjustment of the relative relationship thereof shall also be regarded as the scope of the present invention without substantially changing the technical content.

[0035] In order to better understand the above technical scheme, the exemplary embodiments of the present invention are described in more detail below. Although exemplary embodiments of the present invention are shown, it should be understood that the present invention can be implemented in various forms and should not be limited by the embodiments set forth herein. On the contrary, these embodiments are provided in order to enable a more thorough understanding of the present invention and to enable the scope of the present invention to be fully communicated to those skilled in the art.

[0036] The present invention will be further described below in conjunction with the following examples.

[0037] Example 1

[0038] A TPE micro-foam material, used for a mouse and keyboard wrist pad material, the ingredients are calculated by weight, including:

[0039] 65 parts of hydrogenated styrene-butadiene block copolymer, 12 parts of ethylene-octene copolymer, 8 parts of ethylene-vinyl acetate copolymer, 9 parts of modified filler, 4.5 parts of masterbatch, 5 parts of lubricant, 1.4 parts of foaming agent and 0.7 parts of antioxidant.

[0040] Among them, the brand of hydrogenated styrene-butadiene block copolymer is SEBS YH-503T of Baling Petrochemical; the brand of ethylene-octene copolymer is Dow POE 8407 of the United States; the brand of ethylene-vinyl acetate copolymer is Tosoh EVA625 of Japan; the brand of masterbatch is Cabot PLASBLAK UN6073 of the United States; the lubricant is calcium stearate; the foaming agent is 4,4-oxybisbenzenesulfonyl hydrazide; and the antioxidant is antioxidant 2246.

[0041] Wherein, the preparation method of the modified filler comprises:

[0042] S1. Mix tungsten silicide with a particle size of 100 μm and a hydrogen peroxide solution with a mass fraction of 25%, the mass ratio of tungsten silicide to hydrogen peroxide solution is 1:20, and after ultrasonic treatment for 2 hours, centrifuge, wash and dry to obtain activated tungsten silicide; mix activated tungsten silicide and anhydrous ethanol, add vinyl trimethoxysilane, the mass ratio of activated tungsten silicide, vinyl trimethoxysilane and anhydrous ethanol is 1:0.3:20, reflux and stir for 5 hours, and after the treatment, centrifuge, wash and dry to obtain vinyl-modified tungsten silicide;

[0043] S2, 2-vinylbenzaldehyde and 3-amino-1,2,4-triazole are mixed in toluene, the mass ratio of 2-vinylbenzaldehyde, 3-amino-1,2,4-triazole and toluene is 1.9:1.6:20, nitrogen is used as a protective gas, the temperature is gradually raised to 110° C., under the action of glacial acetic acid, refluxed and stirred for 5 hours, the amount of glacial acetic acid added is 4% of the mass of 2-vinylbenzaldehyde, after the reaction is completed, the solvent is removed under pressure to obtain a vinyl intermediate product;

[0044] S3. Mix the vinyl-modified tungsten silicide and the vinyl intermediate product in tetrahydrofuran, the mass ratio of the vinyl-modified tungsten silicide, the vinyl intermediate product and tetrahydrofuran is 1:1.5:15, nitrogen is used as a protective gas, and an initiator azobisisobutyronitrile is added in an amount of 5% of the mass of the vinyl intermediate product. Heat to 70°C, keep warm and stir for 12 hours, centrifuge, wash and dry to obtain a modified filler.

[0045] The preparation method of the above-mentioned TPE micro-foamed mouse and keyboard wrist pad material comprises the following steps:

[0046] Step 1, weighing hydrogenated styrene-butadiene block copolymer, ethylene-octene copolymer, ethylene-vinyl acetate copolymer, modified filler, masterbatch, lubricant and antioxidant according to weight parts, and mixing them in a mixer at a mixing temperature of 110° C. for 15 minutes;

[0047] Step 2, adding a foaming agent to the mixture of step 1, continuing to maintain the temperature and kneading for 8 minutes, then pouring it into an extruder, and performing extrusion foaming molding at 165° C. to obtain a TPE micro-foamed mouse and keyboard wrist pad material.

[0048] Example 2

[0049] A TPE micro-foam material, used for a mouse and keyboard wrist pad material, the ingredients are calculated by weight, including:

[0050] 55 parts of hydrogenated styrene-butadiene block copolymer, 16 parts of ethylene-octene copolymer, 5 parts of ethylene-vinyl acetate copolymer, 12 parts of modified filler, 2.5 parts of masterbatch, 8 parts of lubricant, 1.1 parts of foaming agent and 1 part of antioxidant.

[0051] Among them, the brand of hydrogenated styrene-butadiene block copolymer is SEBS YH-501T; the brand of ethylene-octene copolymer is POE 8770; the brand of ethylene-vinyl acetate copolymer is EVA 510; the brand of masterbatch is PLASBLAKUN2005; the lubricant is zinc stearate; the foaming agent is azodicarbonamide; and the antioxidant is antioxidant 4010.

[0052] Wherein, the preparation method of the modified filler comprises:

[0053] S1. Mix tungsten silicide with a particle size of 80 μm and a hydrogen peroxide solution with a mass fraction of 20%, the mass ratio of tungsten silicide to hydrogen peroxide solution is 1:15, and after ultrasonic treatment for 1 hour, centrifuge, wash and dry to obtain activated tungsten silicide; mix activated tungsten silicide and anhydrous ethanol, add vinyl trimethoxysilane, the mass ratio of activated tungsten silicide, vinyl trimethoxysilane and anhydrous ethanol is 1:0.2:10, reflux and stir for 4 hours, and after the treatment, centrifuge, wash and dry to obtain vinyl-modified tungsten silicide;

[0054] S2, 2-vinylbenzaldehyde and 3-amino-1,2,4-triazole are mixed in toluene, the mass ratio of 2-vinylbenzaldehyde, 3-amino-1,2,4-triazole and toluene is 1.3:1.1:15, nitrogen is used as a protective gas, the temperature is gradually raised to 100° C., under the action of glacial acetic acid, refluxed and stirred for 3 hours, the amount of glacial acetic acid added is 2% of the mass of 2-vinylbenzaldehyde, after the reaction is completed, the solvent is removed under pressure to obtain a vinyl intermediate product;

[0055] S3. Mix the vinyl-modified tungsten silicide and the vinyl intermediate product in tetrahydrofuran, the mass ratio of the vinyl-modified tungsten silicide, the vinyl intermediate product and tetrahydrofuran is 1:1.2:10, nitrogen is used as a protective gas, and an initiator azobisisobutyronitrile is added in an amount of 3% of the mass of the vinyl intermediate product. Heat to 60°C, keep warm and stir for 8 hours, centrifuge, wash and dry to obtain a modified filler.

[0056] The preparation method of the above-mentioned TPE micro-foamed mouse and keyboard wrist pad material comprises the following steps:

[0057] Step 1, weighing hydrogenated styrene-butadiene block copolymer, ethylene-octene copolymer, ethylene-vinyl acetate copolymer, modified filler, masterbatch, lubricant and antioxidant according to weight parts, and mixing them in a mixer at a mixing temperature of 100° C. for 20 minutes;

[0058] Step 2, adding a foaming agent to the mixture of step 1, continuing to maintain the temperature and kneading for 5 minutes, then pouring it into an extruder, and performing extrusion foaming molding at 180° C. to obtain a TPE micro-foamed mouse and keyboard wrist pad material.

[0059] Example 3

[0060] A TPE micro-foam material, used for a mouse and keyboard wrist pad material, the ingredients are calculated by weight, including:

[0061] 75 parts of hydrogenated styrene-butadiene block copolymer, 8 parts of ethylene-octene copolymer, 10 parts of ethylene-vinyl acetate copolymer, 6 parts of modified filler, 7.5 parts of masterbatch, 3 parts of lubricant, 1.7 parts of foaming agent and 0.2 parts of antioxidant.

[0062] Among them, the brand of hydrogenated styrene-butadiene block copolymer is SEBS YH-602T; the brand of ethylene-octene copolymer is POE 8440; the brand of ethylene-vinyl acetate copolymer is EVA 541; the brand of masterbatch is PLASBLAKEG3807; the lubricant is magnesium stearate; the foaming agent is dinitrosopentamethylenetetramine; and the antioxidant is antioxidant 1076.

[0063] Wherein, the preparation method of the modified filler comprises:

[0064] S1. Mix tungsten silicide with a particle size of 120 μm and a hydrogen peroxide solution with a mass fraction of 30%, the mass ratio of tungsten silicide to hydrogen peroxide solution is 1:20, and after ultrasonic treatment for 3 hours, centrifuge, wash and dry to obtain activated tungsten silicide; mix activated tungsten silicide and anhydrous ethanol, add vinyl trimethoxysilane, the mass ratio of activated tungsten silicide, vinyl trimethoxysilane and anhydrous ethanol is 1:0.4:20, reflux and stir for 6 hours, and after the treatment, centrifuge, wash and dry to obtain vinyl-modified tungsten silicide;

[0065] S2, 2-vinylbenzaldehyde and 3-amino-1,2,4-triazole are mixed in toluene, the mass ratio of 2-vinylbenzaldehyde, 3-amino-1,2,4-triazole and toluene is 2.6:2.2:25, nitrogen is used as a protective gas, the temperature is gradually raised to 115°C, and under the action of glacial acetic acid, refluxed and stirred for 6 hours, the amount of glacial acetic acid added is 6% of the mass of 2-vinylbenzaldehyde, after the reaction is completed, the solvent is removed under pressure to obtain a vinyl intermediate product;

[0066] S3. Mix the vinyl-modified tungsten silicide and the vinyl intermediate product in tetrahydrofuran, the mass ratio of the vinyl-modified tungsten silicide, the vinyl intermediate product and tetrahydrofuran is 1:1.8:20, nitrogen is used as a protective gas, and an initiator azobisisobutyronitrile is added in an amount of 8% of the mass of the vinyl intermediate product. Heat to 60-80°C, keep warm and stir for 16 hours, centrifuge, wash and dry to obtain a modified filler.

[0067] The preparation method of the above-mentioned TPE micro-foamed mouse and keyboard wrist pad material comprises the following steps:

[0068] Step 1, weighing hydrogenated styrene-butadiene block copolymer, ethylene-octene copolymer, ethylene-vinyl acetate copolymer, modified filler, masterbatch, lubricant and antioxidant according to weight parts, and mixing them in a mixer at a mixing temperature of 120° C. for 10 min;

[0069] Step 2, adding a foaming agent to the mixture of step 1, continuing to maintain the temperature and kneading for 10 minutes, then pouring it into an extruder, and performing extrusion foaming molding at 150° C. to obtain a TPE micro-foamed mouse and keyboard wrist pad material.

[0070] Comparative Example 1

[0071] A TPE micro-foam material, which is different from Example 1 in that the modified filler is vinyl-modified tungsten silicide (prepared in the same way as step S1 of Example 1). The rest is the same as Example 1.

[0072] Comparative Example 2

[0073] A TPE micro-foam material, which is different from Example 1 in that the modified filler is a mixture of vinyl-modified tungsten silicide (prepared in the same manner as step S1 of Example 1) and 2-vinylbenzaldehyde in a mass ratio of 1:1.2. The rest is the same as Example 1.

[0074] Comparative Example 3

[0075] A TPE micro-foam material, which is different from Example 1 in that the modified filler is a mixture of vinyl-modified tungsten silicide (prepared in the same manner as step S1 of Example 1) and 3-amino-1,2,4-triazole in a mass ratio of 1:1.2. The rest is the same as Example 1.

[0076] Experimental testing

[0077] The performance of the TPE micro-foam materials prepared in Example 1 and Comparative Examples 1-3 was tested and compared. The tensile strength test was based on ASTM D412, the rebound rate test was based on ASTM D1054, the compression permanent deformation rate test was based on ASTM D395, and the heat deformation temperature test was based on ASTM D648. The test results are shown in Table 1:

[0078] Table 1 Performance of different TPE micro-foam materials

[0079]

[0080] It can be seen from Table 1 that the TPE micro-foam material prepared in Example 1 has higher tensile strength and resilience, lower compression permanent deformation rate, higher thermal deformation temperature, and the tensile strength can still be maintained above 90% after aging treatment. In summary, it can be shown that the TPE micro-foam material prepared in Example 1 of the present invention exhibits more excellent strength, compression resilience, heat resistance and aging resistance.

[0081] In the description of this specification, the description with reference to the terms "one embodiment", "some embodiments", "example", "specific example", or "some examples" etc. means that the specific features, structures, materials or characteristics described in conjunction with the embodiment or example are included in at least one embodiment or example of the present invention. In this specification, the schematic representation of the above terms should not be understood as necessarily being directed to the same embodiment or example. Moreover, the specific features, structures, materials or characteristics described may be combined in any one or more embodiments or examples in a suitable manner. In addition, those skilled in the art may combine and combine different embodiments or examples described in this specification.

[0082] Although the embodiments of the present invention have been shown and described above, it is to be understood that the above embodiments are exemplary and are not to be construed as limitations of the present invention. A person skilled in the art may change, modify, replace and vary the above embodiments within the scope of the present invention.

Claims

1. A TPE micro-foamed mouse and keyboard wrist pad material, characterized in that: Ingredients are calculated by weight and include: 55-75 parts of hydrogenated styrene-butadiene block copolymer, 8-16 parts of ethylene-octene copolymer, 5-10 parts of ethylene-vinyl acetate copolymer, 6-12 parts of modified filler, 2.5-7.5 parts of masterbatch, 3-8 parts of lubricant, 1.1-1.7 parts of foaming agent and 0.2-1 parts of antioxidant; The preparation method of the modified filler comprises: S1. Mix tungsten silicide and hydrogen peroxide solution, ultrasonically treat for 1-3 hours, centrifuge, wash and dry to obtain activated tungsten silicide; mix activated tungsten silicide and anhydrous ethanol, add vinyltrimethoxysilane, reflux and stir for 4-6 hours, and after the treatment, centrifuge, wash and dry to obtain vinyl-modified tungsten silicide; S2, 2-vinylbenzaldehyde and 3-amino-1,2,4-triazole are mixed in toluene, nitrogen is used as a protective gas, the temperature is gradually raised to 100-115°C, and refluxed and stirred for 3-6 hours under the action of glacial acetic acid. After the reaction is completed, the solvent is removed under pressure to obtain a vinyl intermediate product; S3. The vinyl-modified tungsten silicide and the vinyl intermediate product are mixed in tetrahydrofuran, nitrogen is used as a protective gas, an initiator azobisisobutyronitrile is added, the temperature is raised to 60-80° C., the mixture is stirred for 8-16 hours, and then centrifuged, washed and dried to obtain a modified filler.

2. The TPE micro-foamed mouse and keyboard wrist pad material according to claim 1, characterized in that: The brand of the hydrogenated styrene-butadiene block copolymer is one or more combinations of SEBS YH-501T, SEBS YH-502T, SEBS YH-503T, SEBSYH-506T, SEBS YH-602T and SEBS YH-688.

3. The TPE micro-foamed mouse and keyboard wrist pad material according to claim 1, characterized in that: The brand of the ethylene-octene copolymer is one or a combination of POE 8770, POE 8137, POE 8407 and POE 8440.

4. The TPE micro-foamed mouse and keyboard wrist pad material according to claim 1, characterized in that: The brand of the ethylene-vinyl acetate copolymer is one or more combinations of EVA 625, EVA 630, EVA 510 and EVA 541.

5. The TPE micro-foamed mouse and keyboard wrist pad material according to claim 1, characterized in that: The brand of the masterbatch is one of PLASBLAK UN6073, PLASBLAK UN2005 and PLASBLAK EG3807; the foaming agent is one of 4,4-oxybisbenzenesulfonyl hydrazide, azodicarbonamide and dinitrosopentamethylenetetramine.

6. The TPE micro-foamed mouse and keyboard wrist pad material according to claim 1, characterized in that: The lubricant is a mixture of one or more of zinc stearate, magnesium stearate, calcium stearate, and stearic acid; the antioxidant is a mixture of one or more of antioxidant 4010, antioxidant 2246, and antioxidant 1076.

7. The TPE micro-foamed mouse and keyboard wrist pad material according to claim 1, characterized in that: In the S1, the particle size of tungsten silicide is 80-120 μm, the mass fraction of hydrogen peroxide solution is 20%-30%, the mass ratio of tungsten silicide to hydrogen peroxide solution is 1:15-20, and the mass ratio of activated tungsten silicide, vinyltrimethoxysilane and anhydrous ethanol is 1:0.2-0.4:10-20.

8. The TPE micro-foamed mouse and keyboard wrist pad material according to claim 1, characterized in that: In the S2, the mass ratio of 2-vinylbenzaldehyde, 3-amino-1,2,4-triazole and toluene is 1.3-2.6:1.1-2.2:15-25; and the amount of glacial acetic acid added is 2%-6% of the mass of 2-vinylbenzaldehyde.

9. The TPE micro-foamed mouse and keyboard wrist pad material according to claim 1, characterized in that: In S3, the mass ratio of vinyl-modified tungsten silicide, vinyl intermediate product and tetrahydrofuran is 1:1.2-1.8:10-20; and the added amount of initiator azobisisobutyronitrile is 3%-8% of the mass of the vinyl intermediate product.

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