一种高断裂伸长率的宽温域阻尼聚氨酯弹性体及其制备方法

By introducing multiple hydrogen bonds and disulfide bonds into polyurethane elastomers and optimizing the formulation and process, a wide-temperature-range damping polyurethane elastomer with high elongation at break was prepared, solving the problems of insufficient damping performance and low elongation at break in the existing technology, and achieving excellent performance in various temperature scenarios.

CN118834362BActive Publication Date: 2026-07-17BEIJING INST OF TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
BEIJING INST OF TECH
Filing Date
2024-08-15
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polyurethane elastomers have poor damping performance at both room temperature and high temperature, and low elongation at break, making it difficult to meet the needs of industrial applications in various temperature-dependent scenarios.

Method used

By introducing multiple hydrogen bonds and disulfide dynamic bonds, the formulation and process of polyurethane elastomers are optimized to prepare wide-temperature-range damping polyurethane elastomers with high elongation at break. A one-pot, multi-step synthesis process is adopted, using raw materials such as diisocyanate, polydiol, dihydroxydiphenyl disulfide, dimethylacetamide solvent, catalyst, and tartaric acid.

Benefits of technology

It achieves high damping performance (damping coefficient higher than 0.3) at temperatures above -20℃ and elongation at break of over 2300%, meeting the requirements of various working conditions. It possesses excellent damping performance and mechanical strength and is suitable for various temperature-varying scenarios.

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Abstract

本发明涉及聚合物技术领域,尤其是涉及一种高断裂伸长率的低温、室温宽温域阻尼聚氨酯弹性体及其制备方法和应用。本发明与传统聚氨酯弹性体相比在室温极宽温域下有着优异的阻尼性能,在‑20℃以上阻尼因子均高于0.3。如此优异的阻尼性能主要归功于其内部丰富的动态键和多重氢键,动态键和多重氢键的断裂和重组能够增加能量的耗散,同时增加链段的迁移效率,最终得到优异的阻尼性能。本发明的动态键含量可以按需调控,以满足不同的性能要求和工况要求。酒石酸为天然生物原料,使得制备的弹性体有较好的生物相容性和降解性,同时工艺路线为简单的一锅法,可以实现大规模的工业生产。
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