炭基气态汞脱除剂及其制备和应用

By combining the modification of the carbon substrate with modifiers A and B, a carbon-based gaseous mercury remover that can efficiently remove gaseous elemental mercury at room temperature was prepared. This solves the problem of unsatisfactory mercury removal efficiency in existing technologies at high mercury concentrations and achieves efficient and stable mercury adsorption.

CN118949932BActive Publication Date: 2026-07-17CENT SOUTH UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CENT SOUTH UNIV
Filing Date
2024-09-30
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing gaseous mercury removal agents are not efficient and effective at removing mercury at room temperature and high mercury concentrations, making it difficult to meet the needs of high mercury emissions during processes such as polyvinyl chloride (PVC) production and natural gas/gold mining.

Method used

A carbon-based gaseous mercury remover was prepared by liquid-phase impregnation modification of a carbon substrate with modifier A, followed by pyrolysis modification with modifier B. Modifier A is MXn (M is a metal element with a valence of 1, 2 or 3, X is a halogen, and B is elemental sulfur). Active sites were constructed by specific heat treatment temperature and time to achieve efficient mercury removal at room temperature under high mercury conditions.

Benefits of technology

It achieves highly efficient adsorption of gaseous elemental mercury at room temperature, with an adsorption efficiency of >90% over a long period of time. The mercury removal products are stable and suitable for treating waste gas with high mercury concentration.

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Abstract

本发明属于气体汞脱除领域,具体涉及一种炭基气态汞脱除剂的制备方法,先将炭基底经改性剂A浸渍改性,再与改性剂B混合进行热解改性,即得;所述的改性剂A为MXn;其中,M为价态为1、2或3的金属元素;所述的X为卤素,所述的n为M的化合价;所述的改性剂B包括单质硫;所述的热处理的温度在300℃以上。本发明还包括所述的制备方法制得的材料及其在气态汞脱除中的应用。本发明能够构建气态汞吸附的活性位点和物化结构,如此可以使其在高汞、室温条件下仍可表现出理想的气态汞脱除效率和效果。
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