一种用于水体镍络合物深度去除的纳米纤维吸附材料制备方法及镍络合物废水资源化技术

By preparing nanofiber adsorbent materials containing amine and sulfur groups, the problem of low removal efficiency of nickel complexes by nanofibers was solved, achieving efficient removal and regeneration, reducing costs and pollution, and realizing the resource utilization of nickel ions.

CN118949934BActive Publication Date: 2026-07-17CHONGQING UNIVERSITY OF SCIENCE AND TECHNOLOGY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CHONGQING UNIVERSITY OF SCIENCE AND TECHNOLOGY
Filing Date
2024-08-14
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing nanofibers have low removal efficiency for nickel complexes, high processing costs, limited recycling performance, and pose a risk of secondary pollution. Furthermore, nickel ion resource recovery is difficult.

Method used

Using polyvinyl alcohol, polyaniline, and polyacrylonitrile as raw materials, amine- and sulfur-containing nanofiber adsorbent materials are prepared by electrospinning technology. These materials are used for the deep removal of nickel complexes in water, and the nickel ions are recycled through desorption solution to achieve resource utilization.

Benefits of technology

This improved the removal efficiency of nickel complexes, reduced treatment costs, decreased the risk of secondary pollution, and enabled the resource utilization of nickel ions.

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Abstract

本发明涉及纳米纤维吸附材料技术领域,具体公开了一种用于水体镍络合物深度去除的纳米纤维吸附材料制备方法及镍络合物废水资源化技术,包括如下步骤:以聚乙烯醇、聚苯胺、聚丙烯腈、聚丙烯为原料;在聚乙烯醇溶液中加入氧化剂进行反应,随后引入胺基;在聚苯胺溶液中通过交联剂引入胺基;将聚丙烯腈溶液引入胺基;在聚丙烯基底中引入胺基;加入含硫试剂制得含硫吸附位点的聚合物的纺丝液;以纺丝液为原料,将其制为纳米纤维,经洗涤、干燥,即制得用于水体镍络合物深度去除的纳米纤维吸附材料。提供强大的吸附能力,能够有效的吸附废水中的镍络合物,提高镍络合物的去处效率,对镍络合物具有更高的选择性和亲和力。
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