一种利用废铬渣催化热解废橡塑及还原六价铬的方法

By utilizing waste chromium slag for catalytic pyrolysis of waste rubber and plastics, combined with microwave technology and carbon dioxide gas supply, the problems of low pyrolysis efficiency of waste plastics and waste rubber and low reduction efficiency of hexavalent chromium have been solved, realizing efficient resource utilization of waste and environmental protection.

CN119078025BActive Publication Date: 2026-07-17QINGDAO UNIV OF TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
QINGDAO UNIV OF TECH
Filing Date
2024-08-30
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies have low pyrolysis efficiency for waste plastics and waste rubber, and insufficient harmless treatment and resource utilization of waste chromium slag, especially low reduction efficiency of hexavalent chromium.

Method used

Using waste chromium slag as a catalyst, and through an integrated catalytic reforming generator and a microwave reactor, combined with ex-situ and in-situ catalytic pyrolysis technologies, the catalytic selectivity of waste chromium slag and the microwave absorption properties of pyrolysis residue are utilized. Combined with carbon dioxide supply to generate reducing gas, the catalytic reforming of high-temperature oil and gas and the reduction of hexavalent chromium are achieved.

Benefits of technology

It increased the yield of waste rubber and plastic pyrolysis oil, promoted the dual resource utilization of waste rubber and plastic and chromium slag, improved pyrolysis efficiency and the reduction rate of hexavalent chromium, and realized the dual advantages of high-value resource utilization of waste and environmental protection.

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Abstract

本发明公开了一种利用废铬渣催化热解废橡塑及还原六价铬的方法,涉及固废产物综合利用技术领域。其主要包括进料装置、催化改质一体化发生器和微波反应器,其中,催化改质一体化发生器的发生器壳体内部设有进料螺杆和铬渣破碎机构,废橡塑和废铬渣在进料螺杆和铬渣破碎机构的作用下实现废橡塑的热解、热解残渣细化和铬渣的连续破碎;微波反应器与催化改质一体化发生器相连,利用废橡塑热解残渣作为高效的“吸波材料”,通过高温和还原反应实现六价铬的无害化处理。本发明不仅能够利用铬渣的催化选择性提高轻质油的产率,同时利用废橡塑热解后形成的残渣作为还原Cr6+的载体,有效促进了废橡塑和铬渣的双重资源化利用。
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