一种改性钛酸铋钠-钛酸钡基陶瓷材料及制备方法、应用

By modifying sodium bismuth titanate-barium titanate-based ceramics with the high entropy effect, the problems of low breakdown strength and low energy storage efficiency of sodium bismuth titanate-barium titanate-based energy storage ceramics were solved, achieving the effects of high breakdown strength and high energy storage density.

CN119118659BActive Publication Date: 2026-07-17JILIN UNIVERSITY

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
JILIN UNIVERSITY
Filing Date
2024-09-11
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing sodium bismuth titanate-barium titanate-based energy storage ceramics have low breakdown strength and energy storage efficiency, making it difficult to meet the miniaturization requirements of electronic products.

Method used

By utilizing the high entropy effect of multiple elements entering the same lattice position, an energy storage ceramic with the chemical formula (1-x)(Na0.5Bi0.5)1-yBayTiO3-xLa(Mg2/5Al2/5Ta1/5)O3 was prepared through solid-state reaction and sintering. The perovskite structure was modified by BaTiO3-La(Mg2/5Al2/5Ta1/5) composite ions to enhance the temperature stability and energy storage efficiency of the material.

Benefits of technology

The breakdown strength and energy storage density of the ceramic material were improved, with a breakdown strength of 255 kV/cm, an effective energy storage density of 5.1 J/cm3, and an energy storage efficiency of 92%.

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Abstract

本发明适用于储能材料技术领域,提供了一种改性钛酸铋钠‑钛酸钡基陶瓷材料的制备方法,包括以下步骤:配料:将碳酸钠、氧化铋、氧化钛、碳酸钡、氧化镧、氧化镁、氧化铝和氧化钽按照化学式(1‑x)(Na0.5Bi0.5)1‑yBayTiO3‑xLa(Mg2 / 5Al2 / 5Ta1 / 5)O3的摩尔比混合得到混合物,其中0.001≤x≤0.20,0.01≤y≤0.10;混料;烘干;固相反应;球磨;烘干;造粒成型;排胶;烧结。本发明还提供了一种改性钛酸铋钠‑钛酸钡基陶瓷材料及其在制备电介质材料中的应用。本发明提供的储能陶瓷材料击穿强度可以达到255kV / cm,有效储能密度可以达到5.1J / cm3,储能效率达到92%。
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