一种多色彩钴镍氢氧化物电致变色复合膜层的制备方法

By introducing V2O5 and constructing a MnO2 bonding layer into the Co(OH)2/Ni(OH)2 thin film, the problems of insufficient variable color and poor adhesion of the Co(OH)2/Ni(OH)2 electrochromic thin film were solved, realizing the preparation of multi-color and highly stable composite film layers and broadening the application range.

CN119143406BActive Publication Date: 2026-07-17CHINA SHIPBUILDING INDUSTRY CORPORATION NO725 RESEARCH INSTITUTE

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
CHINA SHIPBUILDING INDUSTRY CORPORATION NO725 RESEARCH INSTITUTE
Filing Date
2024-09-13
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing Co(OH)2/Ni(OH)2 electrochromic films have limited color options, lack vibrant colors, and exhibit insufficient adhesion to the substrate, thus affecting cycle stability.

Method used

By introducing V2O5 and MnO2 into Co(OH)2/Ni(OH)2 electrochromic films, and by controlling the preparation parameters of V2O5 and constructing an MnO2 bonding layer on the substrate, multi-color composite films were prepared using a simple cyclic voltammetry and electrodeposition method, thus optimizing the film structure and adhesion.

Benefits of technology

This enriches the variable color range of the thin film, extending it from blue-green to orange-red, improving the film's photoelectric properties and cycle stability, enhancing the adhesion between the film and the substrate, and strengthening its application potential in camouflage and stealth materials.

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Abstract

本发明涉及电致变色材料领域,具体为一种多色彩钴镍氢氧化物电致变色复合膜层的制备方法,包括以下具体步骤:S1:配制钴盐和镍盐的混合溶液;S2:制备Co(OH)2 / Ni(OH)2电致变色薄膜;S3:沉积结束后,去离子水冲洗表面,在烘箱中烘干;S4:配制电沉积熔液的混合溶液;调整混合溶液的pH至2‑4;S5:使用循环伏安法进行沉积;S6:沉积结束后,在烘箱中烘干。本发明制备工艺将钴镍氢氧化物与钒氧化物等电致变色材料结合,通过调控优化V2O5制备参数,使用简单循环伏安法和电沉积法即可获得可变色彩丰富、光电性能优越的复合膜。
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