一种用于分离染料与无机盐的聚酰胺膜制备方法

By treating the polyamide membrane support layer with a solution of 2,4,6-triaminopyrimidine and 1,3,5-pyromellitic acid chloride, a high-flux, stable polyamide membrane is formed, which solves the problems of low flux and poor repeatability of traditional membranes in dye wastewater treatment, and achieves efficient separation of dyes and inorganic salts and improved stability.

CN119236711BActive Publication Date: 2026-07-17NORTH CHINA UNIV OF WATER RESOURCES & ELECTRIC POWER

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
NORTH CHINA UNIV OF WATER RESOURCES & ELECTRIC POWER
Filing Date
2024-07-26
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Traditional polyamide nanofiltration membranes have low flux in dye wastewater treatment, making it difficult to achieve efficient separation of dyes and inorganic salts. They also have poor repeatability and cannot be used stably under high pressure.

Method used

The polyamide membrane support layer was soaked and heated to crosslink with an aqueous solution of 2,4,6-triaminopyrimidine and an oil solution of 1,3,5-pyrimidinetricarboxyl chloride to form a polyamide active layer, which improved the membrane flux and separation effect, and enhanced its repeatability and stability.

Benefits of technology

The prepared polyamide membrane has high flux, can effectively separate dyes and inorganic salts, and has good chlorine resistance and antifouling properties, making it suitable for large-scale production.

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Abstract

一种用于分离染料与无机盐的聚酰胺膜制备方法,依次采用水相溶液和油相溶液对聚酰胺膜支撑层进行浸泡,使其表面生成聚酰胺活性层,最后经加热交联获得聚酰胺膜,所述水相溶液为2,4,6‑三氨基嘧啶溶解于碱性溶液得到的溶液,该方法制备的聚酰胺膜不仅通量高且能实现染料与盐很好的分离,而且具有良好的耐氯和抗有机污染性能,同时,聚酰胺膜重复性好,使聚酰胺膜成膜更加稳定,能够进行大规模生产。
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