一种高强韧和快速自恢复的抗溶胀水凝胶及其作为应变传感器的应用

By preparing hydrogels containing carboxyl groups and benzene rings, polymerizable monomers, multivalent ionic salts, and photoinitiators, a hierarchical heterostructure with π-π stacking and cation-π interactions is formed, which solves the problems of insufficient mechanical properties and self-healing ability of hydrogels in underwater environments, and achieves high strength and toughness, rapid self-healing and excellent strain sensing performance.

CN119264320BActive Publication Date: 2026-07-17SHANGHAI JIAOTONG UNIV

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
SHANGHAI JIAOTONG UNIV
Filing Date
2024-11-07
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing hydrogel strain sensors have low mechanical properties in underwater environments and insufficient self-recovery capabilities. Swelling behavior leads to a decrease in sensing reliability.

Method used

A high-strength, tough, and rapidly self-healing anti-swelling hydrogel was prepared by polymerizing a polymerizable monomer containing carboxyl and benzene rings, a multivalent ionic salt, and a photoinitiator in dimethyl sulfoxide to form a hierarchical heterostructure with π-π stacking and cation-π interactions. Combined with COO--Mn+ metal coordination bonds, a rigid-flexible hydrogel network was formed.

Benefits of technology

It significantly enhances the mechanical strength and toughness of the hydrogel, improves its anti-swelling ability and self-healing properties, endows the hydrogel with excellent strain sensing performance, and realizes underwater information transmission.

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Abstract

本发明公开了一种高强韧和快速自恢复的抗溶胀水凝胶及其作为应变传感器的应用。将含羧基的可聚合单体、含苯基或苯氧基的丙烯酸酯单体、多价离子盐和光引发剂溶解于二甲基亚砜(DMSO)中,制备均匀的前驱体溶液。将前驱体溶液在惰性气氛下紫外光聚合得到有机预凝胶。将有机预凝胶浸泡在大量水中,通过溶剂交换除去凝胶中的溶剂后获得最终的水凝胶。水凝胶具有卓越的机械性能、传感性能和抗溶胀性能,被用作应变传感器在水下环境中传输基于摩斯密码的信息。
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