Preparation method of high color depth and soft feeling electron beam curing paint and application thereof in textile coloring

Abstract

The application discloses an electron beam silicon modified coloring particle and a preparation method and application thereof, and belongs to the technical field of textile printing and dyeing. The coloring particle is formed by taking a small molecule dye or pigment as a core and a polymer capable of being electron beam radiation cured as a shell, and a coloring dye liquid is prepared by using the coloring particle to perform padding dyeing on a textile substrate. The silicon modified monomer is used for modifying the coloring particle, so that the coloring particle is endowed with soft and breathable performance, carboxyl groups are introduced into the shell layer, cationic dyes are adsorbed, the dyeing rate of the dyes is improved, and high color depth is realized. The application has the characteristics of fast curing speed and low energy consumption, solves the problems of long traditional textile coloring and curing process, high energy consumption, and the fact that the light curing coloring technology is limited by the light penetration ability and is difficult to cure a colored system, simultaneously realizes high color depth and soft hand feeling, and solves the problem of the difficulty of electron beam curing in textile application.

Description

Technical Field

[0001] This invention relates to a method for preparing an electron beam curable coating with high color depth and soft hand feel, and its application in textile coloring, belonging to the field of fine chemical technology. Background Technology

[0002] Traditional textile coloring and curing methods primarily involve thermal curing and photocuring. However, these methods have certain limitations. For example, the thermal curing process in ZL107938387B is time-consuming, energy-intensive, and has high production costs. Photocuring, on the other hand, utilizes ultraviolet (UV) light sources and is characterized by its speed and low energy consumption, as seen in ZL103788771B and ZL103788771B. However, light attenuation is closely related to the properties of the irradiated material, and light penetration is limited by light penetration ability. When the transparency of the material decreases, light penetration is hindered, especially for opaque or thick materials, where light penetration and energy deposition depth are significantly reduced, making photocuring difficult to apply to colored systems. With increasing demands for energy conservation and emission reduction, electron beam curing, as a new type of green curing technology with fast curing speed, low energy consumption, and no VOC emissions, has found wide application in industries such as printing, packaging, electronics, and automotive manufacturing.

[0003] High water consumption, high energy consumption, and high pollution have always been key issues restricting the development of the textile industry. Therefore, a low-energy and low-water-consumption green dyeing technology for textiles is urgently needed. Electron beam, as a short-process, low-energy curing technology, has seen limited application in textile coloring. Due to the flexible and porous nature of textiles, it is necessary to maintain a soft hand feel and breathability while coloring. However, current electron beam curing colorants do not consider hand feel and breathability, resulting in a stiff hand feel and poor breathability. Furthermore, dyeing fibers involves adsorption, diffusion, and fixation; however, in electron beam curing, the short dyeing process leads to low dye utilization and low color depth. Summary of the Invention

[0004] [Technical Issues]

[0005] Traditional thermosetting coloring technology for textiles is time-consuming and energy-intensive, failing to meet the requirements of low-carbon production. Photocuring coloring technology is limited by the light's penetrability, making it difficult to cure colored systems. Existing electron beam curing colorants result in fabrics that are stiff to the touch, have poor breathability, and have low dye utilization, leading to shallow color depth.

[0006] [Technical Solution]

[0007] To address the aforementioned problems, this invention designs and develops electron beam-curable silicon-modified coloring particles, electron beam-curable coatings, and their applications in textile coloring. Specifically, this invention relates to a polymeric colorant suitable for electron beam curing of textiles. Small molecule colorants are covalently "anchored" within polymer microspheres in polymer chains, protecting the dye while simultaneously imparting desired functionality through polymer structure adjustment. The core material is a colored pigment or insoluble dye, and the shell material is a polymer that can be cured by electron beam irradiation, including radiation-curable polymer monomers, carboxyl-containing acrylic monomers, and polymerizable silicon monomers. Utilizing the electrostatic adsorption of carboxyl groups and cationic dyes, and in combination with cationic dyes, the cationic dyes can adsorb around the coloring particles, thereby improving the dye uptake rate. Furthermore, the softness and low surface energy of polymerizable silicon monomers impart soft and breathable properties to the coating.

[0008] To achieve the above objectives, the present invention first provides electron beam-curable silicon-modified coloring particles; the coloring particles are composed of a core material and a wall material; the core material includes a dye; the wall material includes an electron beam radiation-polymerizable grafted polymer. The electron beam radiation-polymerizable grafted polymer is copolymerized from a radiation-curable polymer monomer, a carboxyl-containing acrylic monomer, and a polymerizable silicon monomer.

[0009] In one embodiment of the present invention, the mass ratio of the radiation-curable polymer monomer, the carboxyl-containing acrylic monomer, and the polymerizable silicone monomer is 70-99:1-15:0.5-5.

[0010] In one embodiment of the present invention, the core-shell ratio of the core material to the wall material is 1:(1-4).

[0011] In one embodiment of the present invention, the dye includes at least one of the following: alkene double bond anthraquinone type dye, triarylmethane dye, disperse violet 93, disperse blue 73, disperse blue 60, disperse yellow 64, disperse red 79, carbon black, phthalocyanine pigment, titanium dioxide, and chrome green.

[0012] In one embodiment of the present invention, the radiation-curable polymer monomer includes at least one of acrylonitrile, polyurethane, ethylene-vinyl acetate copolymer (EVA), isobornyl acrylate, hydroxyethyl acrylate, hydroxyethyl methacrylate, methacrylic acid, and glycidyl methacrylate.

[0013] In one embodiment of the present invention, the acrylic monomer having a carboxyl group includes at least one of acrylic acid, methacrylic acid, and vinylacrylic acid.

[0014] In one embodiment of the present invention, the silicon polymerizable monomer includes at least one of vinyltrimethoxysilane (VTMS), vinyl polydimethylsiloxane (V-PDMS), divinyltetramethyldisiloxane (DVMS), dimethylvinylchlorosilane, and vinyltriisopropoxysilane.

[0015] This invention also provides a method for preparing electron beam-cured silicon-modified coloring particles, comprising the following steps:

[0016] 4) Oil phase preparation: Add polymer monomers, acrylic monomers and silicone polymerizable monomers to a beaker, mix thoroughly and stir evenly to prepare the oil phase;

[0017] 5) Preparation of nano-dispersions: Mix the core material and dispersant evenly, and grind and disperse them to 90-130 nm using a grinder at a speed of 5000-9000 rpm to obtain nano-dispersions;

[0018] 6) Aqueous phase preparation: Take the nano-dispersion obtained in step (2), add dispersant and deionized water, and stir evenly to prepare an aqueous phase;

[0019] 4) Emulsion preparation: The oil phase prepared in step 1) is slowly added to the aqueous phase prepared in step 3), and emulsified using a high-speed emulsifier. The emulsified emulsion is then transferred to a three-necked flask and mechanically stirred to obtain the emulsion.

[0020] 5) Preparation of electron beam cured colored particles: The emulsion obtained in step 3) is heated, the rotation speed is reduced, and the initiator is slowly added to the emulsion multiple times to react and obtain an electron beam cured colored particle dispersion; after filtration, centrifugation, washing and drying, electron beam cured colored particles are obtained.

[0021] In one embodiment of the present invention, the core-to-shell ratio of the core material to the wall material is 1:1-4; wherein, the mass fraction of the acrylic monomer with carboxyl groups in the oil phase is 1-15%; the mass fraction of the silicone polymerizable monomer in the oil phase is 0.5-5%; and the mass fraction of the radiation-curable polymer monomer in the oil phase is 70-99%.

[0022] In one embodiment of the present invention, in step (2), the dispersant includes one or more of sodium lignosulfonate, DM1501, Span 20, Span 40, Span 60, DNS-86, SR-10, TMN-10, TMN-6, sodium p-styrenesulfonate, and DNS-628, and the mass ratio of the dispersant to the core material is 1:(0.5-3).

[0023] In one embodiment of the present invention, in step (3), the mass ratio of the nano-dispersion, the dispersant and the water is 1:0.02-0.1:3-5.

[0024] In one embodiment of the present invention, in step (4), the mass ratio of the oil phase to the water phase is 1:7-15.

[0025] In one embodiment of the present invention, in step (5), the initiator includes at least one of benzoyl peroxide, azobisisobutyronitrile, azobisisoheptanenitrile, persulfate, and azobisisobutyramidine dihydrochloride.

[0026] In one embodiment of the present invention, in step (5), the initiator accounts for 1-5% of the mass fraction of the oil phase.

[0027] In one embodiment of the present invention, in step (5), the reaction temperature is 60-80°C and the reaction time is 5-7h.

[0028] In one embodiment of the present invention, the particle size of the electron beam cured silicon modified coloring particles is 100-500 nm.

[0029] The present invention also provides an electron beam curable coating, wherein the coating comprises, by mass percentage, 5-20% electron beam curable coloring particles, 1-10% cationic dye, 1-5% dispersant, 1-10% crosslinking agent, and the balance deionized water.

[0030] The present invention also provides an application of the above-mentioned electron beam curing coating in textile coloring, wherein the electron beam curing coating is applied to the textile by padding and then electron beam curing is performed.

[0031] In one embodiment of the present invention, when finishing textiles by padding, the roll-off rate is controlled at 70-100%, and electron beam curing can be used to obtain colored fabrics.

[0032] The present invention also provides an electron beam curable coating, wherein the coating comprises, by mass percentage, 5-20% electron beam curable coloring particles, 1-10% cationic dye, 1-5% dispersant, 1-10% crosslinking agent, 0.5-10% thickener and the balance being deionized water.

[0033] The present invention also provides an application of the above-mentioned electron beam curing coating in textile coloring, wherein the electron beam curing coating is applied to textiles by printing or spraying and then electron beam curing is performed.

[0034] In one embodiment of the present invention, when finishing the fabric by printing or spraying, the viscosity of the coating is controlled at 100-1000 cps, and the coating is applied to the textile by printing or spraying, and then electron beam curing is performed to obtain the colored fabric.

[0035] In one embodiment of the present invention, the printing method is one of screen printing, roller printing, or digital inkjet printing.

[0036] In one embodiment of the present invention, the spraying method is to use a spray gun to spray on a room temperature dry fabric at intervals of 10-30cm, with a spraying speed of 10-30cm / s, spraying in small amounts multiple times, and the spraying thickness is 20-200μm.

[0037] In one embodiment of the present invention, the crosslinking agent includes one or more of hydroxyethyl acrylate, trimethylolpropane triacrylate, hydroxyethyl methacrylate, N-hydroxymethylacrylamide, N,N-dimethylacrylamide, acrylic acid, and dodecyl methacrylate.

[0038] In one embodiment of the present invention, the thickener includes one or more of sodium alginate, xanthan gum, starch derivatives, carboxymethyl cellulose (CMC), methyl cellulose, and polyacrylic acid polymers.

[0039] In one embodiment of the present invention, the cationic dye includes one or more of cationic yellow X-8GLN, cationic golden yellow X-GL, cationic red GTL, cationic brilliant blue RL, cationic turquoise blue GB, cationic black WHL, and cationic blue M-RL.

[0040] In one embodiment of the present invention, the radiation dose of the electron beam curing is 10kGy-80kGy, and the curing time is 0.1-3s.

[0041] The beneficial effects of this invention are as follows:

[0042] (1) This invention provides a method for preparing an electron beam curable coating with high color depth and soft hand feel and its application in textile coloring. By using small molecule dyes or pigments as the core and an electron beam curable polymer as the shell to form coloring particles, the prepared coloring particles can be mixed with other dyes, dispersants, crosslinking agents, etc. to prepare an electron beam curable coloring coating. The coloring coating is used to impregnate and dye textile substrates, and the fabric is cured under electron beam conditions, which can greatly reduce curing energy consumption.

[0043] (2) Adding silicon polymerizable monomers to the wall material and using the coating composed of the prepared coloring particles for dyeing results in fabrics with good softness and good air permeability, with the air permeability reaching up to 93.2% of that before dyeing.

[0044] (3) The addition of acrylic monomers with carboxyl groups introduces carboxyl groups into the shell. Carboxyl groups can adsorb cationic dyes, improve the dye uptake rate, and achieve high color depth.

[0045] (4) This invention has the characteristics of fast curing speed and low energy consumption, which solves the problems of long curing process, high energy consumption and light curing coloring technology being limited by the light penetration ability and difficult to cure colored systems. At the same time, it achieves high color depth and soft hand feel, and solves the problem of electron beam curing in textile applications. Detailed Implementation

[0046] The present invention will be further described below through specific embodiments, but the implementation of the present invention is not limited thereto.

[0047] Example 1:

[0048] (1) A method for preparing electron beam cured silicon-modified colored particles

[0049] Weigh 30g of Dispersible Yellow 64, 45g of dispersant DNS-86, and 225g of water. Add zirconium beads (1 / 3 of the total volume) and grind in a horizontal mill at 6000rpm until the particle size is 110nm to obtain a nano-dispersion. Add 10g of the nano-dispersion to a beaker, add 35g of deionized water and 0.5g of dispersant DNS-86 to prepare the aqueous phase. Weigh 2g of acrylonitrile, 1g of hydroxyethyl acrylate, 0.3g of acrylic acid, and 0.09g of vinyltrimethoxysilane, mix and stir evenly to obtain the oil phase.

[0050] The aqueous phase was placed in a three-necked flask and mechanically stirred at 600 rpm. The oil phase was slowly added to the system and stirred until homogeneous. The temperature was raised to 70°C, and 3 mL of an aqueous solution containing 0.05 g of azobisisobutylamidine dihydrochloride was added at a rate of 20 s / drop. After reacting for 2 h, another 2 mL of an aqueous solution containing 0.05 g of azobisisobutylamidine dihydrochloride was added. After reacting for another 3 h, another 3 mL of an aqueous solution containing 0.05 g of azobisisobutylamidine dihydrochloride was added. After reacting for 1 h, the mixture was cooled to room temperature, filtered, centrifuged, and washed to obtain electron beam-cured colored particles.

[0051] (2) Preparation method of electron beam cured coating

[0052] Weigh out the electron beam curable coloring particles prepared in Example 1, the amount of which is 10% of the coating. Add 3% of cationic yellow 28 by weight of the coating, 10% of trimethylolpropane triacrylate by weight of the coating, 5% of dispersant SR-10 by weight of the coating, and the balance deionized water to prepare the electron beam curable coating.

[0053] (3) Application of electron beam cured coatings in textile coloring

[0054] The electron beam curable coating prepared in step (2) was applied to the fabric by two dips and two nips, and the liquid content was controlled to be 90%. Electron beam curing was carried out with an energy of 50 kGy and a curing time of 1 s to obtain electron beam cured colored fabric.

[0055] The air permeability, K / S value, fabric strength, dye grafting rate, color fastness, and hand feel of the fabrics prepared by the above method were evaluated. Air permeability test: The air permeability of the fabric was tested using an air permeability meter according to GB / T5453-1997 "Textiles - Determination of Air Permeability of Fabrics". The K / S value was tested using a Datacolor 650 colorimeter at two randomly selected points on the fabric; the value indicates the depth of color. Hand feel performance was tested using a Phabrometer 3 instrument according to standard FBW04003. Rubbing fastness was tested according to the method in GB / T 3920—2008.

[0056] Example 2

[0057] Weigh out 10% of the electron beam-cured coloring particles prepared in Example 1, add 5% of the dispersant SR-10, 10% of the coating mass, 10% of the thickener DM-5221G, and the remainder deionized water, controlling the coating viscosity at 800 cps to obtain the printing coating. Print the coating on the fabric using screen printing, followed by electron beam curing at an energy of 50 kGy for 1 s to obtain the electron beam-cured colored fabric.

[0058] Example 3

[0059] Weigh out the electron beam cured coloring particles prepared in step (1) of Example 1, the amount of which is 10% of the coating mass. Add 5% of the dispersant SR-10, 10% of the coating mass of trimethylolpropane triacrylate and the balance water to obtain the spray coating. Apply the coating to the fabric surface by spraying at 30cm intervals and at a spraying speed of 10cm / s. Spray in small amounts multiple times. After the coating is uniform, perform electron beam curing with an energy of 50kGy and a curing time of 1s to obtain the electron beam cured coloring fabric.

[0060] Example 4

[0061] The acrylonitrile in step (1) of Example 1 was adjusted to be an ethylene-vinyl acetate copolymer.

[0062] Example 5

[0063] The trimethylolpropane triacrylate in step (2) of Example 1 was changed to dodecyl methacrylate.

[0064] Example 6

[0065] The electron beam curing energy of Example 1 was adjusted to 70 kGy, while other conditions remained unchanged.

[0066] Comparative Example 1

[0067] The electron beam curing energy in Example 1 was adjusted to 5 kGy, while other conditions remained unchanged.

[0068] Comparative Example 2

[0069] The electron beam curing energy in Example 1 was adjusted to 100 kGy, while other conditions remained unchanged.

[0070] Comparative Example 3

[0071] The difference between Comparative Example 3 and Example 1 is that in step (2), the electron beam curing colored particles prepared in Example 1 are weighed out in an amount of 10% of the coating mass, 10% of trimethylolpropane triacrylate is added, 5% of dispersant SR-10 and the remainder deionized water are added to prepare the coating, and the coating is prepared by two dips and two pads, controlling the liquid content to 90%, drying at 60°C, and then baking at 160°C for 3 minutes.

[0072] Comparative Example 4

[0073] The difference between Comparative Example 3 and Example 1 is that in step (2), the electron beam curable coloring particles prepared in Example 1 are weighed out in an amount of 10% of the coating mass, 10% of trimethylolpropane triacrylate is added, 5% of SR-10 and the remainder deionized water are added, and the two dips and two nips are used to control the liquid content to 90%, and the mixture is cured with ultraviolet light in the 465nm band at a distance of 15cm for 5min.

[0074] Comparative Example 5

[0075] The amount of trimethylolpropane triacrylate in step (2) of Example 1 was adjusted to 0%, while other conditions remained unchanged.

[0076] Comparative Example 6

[0077] The electron beam curing coloring particles in Example 1 were changed to Disperse Yellow 64, while other conditions remained unchanged.

[0078] Comparative Example 7

[0079] The amount of cationic yellow 28 in Example 1 was adjusted to 0%, while other conditions remained unchanged.

[0080] Comparative Example 8

[0081] The spray coating in step (2) of Example 1 was adjusted to be an electron beam cured coating. This coating is composed of 50% polyurethane acrylate, 15% tripropylene glycol diacrylate, 15% pentaerythritol triacrylate, 5% pigment yellow 139, 10% dispersant BYK-163, 2% leveling agent VOK-3777 and 3% adhesion promoter dh-7340, with other conditions remaining unchanged.

[0082] Comparative Example 9

[0083] The amount of vinyltrimethoxysilane in Example 1 was adjusted to 0g, while other conditions remained unchanged.

[0084] Comparative Example 10

[0085] The preparation method of electron beam-cured colored particles in Example 1 was adjusted as follows: 12g of acrylonitrile, 2g of acrylic acid, and 0.6g of vinyltrimethoxysilane were weighed, and 1g of Dispersible Yellow 64 was dissolved in the system to prepare an oil phase; 10g of dispersant DNS-86 and 25g of water were dissolved evenly to prepare an aqueous phase. The aqueous phase was placed in a three-necked flask and stirred evenly at 600rpm. The oil phase was slowly added to the system, the temperature was raised to 70℃, and 5ml of acrylonitrile solution containing 0.8g of azobisisobutyronitrile was added at a rate of 20s / drop. The reaction was allowed to proceed for 5h; the mixture was cooled to room temperature, filtered, centrifuged, and washed to obtain electron beam-cured colored particles.

[0086] Table 1 Properties of Electron Beam Cured Colored Fabrics

[0087]

[0088] As can be seen from Examples 1 and 6 and Comparative Examples 1 and 2, if the electron beam radiation intensity is too low, the dye curing effect cannot be achieved. Increasing the electron beam radiation intensity can slightly improve the dye grafting rate and K / S value, but it will seriously damage the fabric.

[0089] As can be seen from Example 1 and Comparative Example 3, although electron beam radiation curing is slightly inferior to high temperature curing in terms of K / S value and color fastness, its energy consumption is significantly reduced.

[0090] As can be seen from Example 1 and Comparative Example 4, electron beam curing can solve the problem of difficult curing of colored systems in UV curing systems and is superior to UV curing in all aspects.

[0091] As can be seen from Example 1 and Comparative Example 6, electron beam curing causes small molecule dyes to decompose and cannot complete curing grafting. Using polymers to covalently anchor the dyes can avoid the decomposition problem, thereby improving the grafting rate of the colored particles.

[0092] As can be seen from Example 1 and Comparative Example 7, the use of cationic dyes in combination can significantly improve the dyeing rate and K / S value. The anionic groups on the surface of the colored particles attract cationic dyes, thereby improving the color depth.

[0093] As can be seen from Example 1 and Comparative Example 8, compared with commercially available electron beam curing colorants, the colorant of this invention has significantly improved hand feel and breathability retention.

[0094] As demonstrated in Example 1 and Comparative Example 9, the use of silane helps to increase the grafting rate and significantly increases the hand feel and breathability retention of the treated fabric.

[0095] As can be seen from Example 1 and Comparative Example 9, preparing the core material into a nano-dispersion can significantly improve the dyeing rate of the fabric, and the hand feel and breathability retention of the treated fabric are also significantly increased.

[0096] The embodiments provided above are not intended to limit the scope of the invention, nor are the described steps intended to limit the order of execution. Any obvious modifications made to the invention by those skilled in the art based on existing common knowledge also fall within the scope of protection defined by the claims.

Claims

1. An electron beam curable coating, characterized in that, By mass percentage, its components include 5-20% electron beam cured coloring particles, 1-10% cationic dye, 1-5% dispersant, 1-10% crosslinking agent, 0-10% thickener, and the balance deionized water. The electron beam cured coloring particles are composed of a core material and a wall material. The core material includes dye. The wall material includes an electron beam radiation-polymerizable grafted polymer. The electron beam radiation-polymerizable grafted polymer is copolymerized from radiation-curable polymer monomers, carboxyl-containing acrylic monomers, and polymerizable silicone monomers.

2. The electron beam curable coating according to claim 1, characterized in that, The mass ratio of the radiation-curable polymer monomer, the carboxyl-containing acrylic monomer, and the polymerizable silicone monomer is 70-99:1-15:0.5-5. The radiation-curable polymer monomer includes at least one of acrylonitrile, polyurethane, ethylene-vinyl acetate copolymer, isobornyl acrylate, hydroxyethyl acrylate, hydroxyethyl methacrylate, methacrylic acid, and glycidyl methacrylate. The carboxyl-containing acrylic monomer includes at least one of acrylic acid, methacrylic acid, and vinylacrylic acid. The polymerizable silicone monomer includes at least one of vinyltrimethoxysilane, vinyl polydimethylsiloxane, divinyltetramethyldisiloxane, dimethylvinylchlorosilane, and vinyltriisopropoxysilane.

3. The electron beam curable coating according to claim 1, characterized in that, The core-to-shell ratio of the core material to the wall material is 1:1-4. The core material includes a dye, which includes at least one of triarylmethane dyes, Disperse Violet 93, Disperse Blue 73, Disperse Blue 60, and Disperse Yellow 64.

4. The electron beam curable coating according to claim 1, characterized in that, The method for preparing the electron beam-cured colored particles includes the following steps: 1) Oil phase preparation: Add polymer monomers, acrylic monomers and polymerizable silicone monomers to a beaker, mix thoroughly and stir evenly to prepare the oil phase; 2) Preparation of nano-dispersions: The core material and dispersant are mixed evenly and then ground and dispersed to 90-130 nm using a grinder at a speed of 5000-9000 rpm to obtain nano-dispersions; 3) Aqueous phase preparation: Take the nano-dispersion obtained in step 2), add dispersant and deionized water, and stir evenly to prepare an aqueous phase; 4) Emulsion preparation: The oil phase prepared in step 1) is slowly added to the aqueous phase prepared in step 3), the mass ratio of the oil phase to the aqueous phase is 1:7-15, and emulsification is performed using a high-speed emulsifier. The emulsified emulsion is then transferred to a three-necked flask and mechanically stirred to obtain the emulsion. 5) Preparation of electron beam cured colored particles: The emulsion obtained in step 4) is heated, the rotation speed is reduced, and the initiator is slowly added to the emulsion multiple times to react and obtain an electron beam cured colored particle dispersion; after filtration, centrifugation, washing and drying, electron beam cured colored particles are obtained.

5. The electron beam curable coating according to claim 4, characterized in that, In step (2), the dispersant includes one or more of sodium lignosulfonate, DM1501, Span 20, Span 40, Span 60, DNS-86, SR-10, TMN-10, TMN-6, sodium p-styrenesulfonate, and DNS-628, and the mass ratio of the dispersant to the core material is 1:0.5-3.

6. The electron beam curable coating according to claim 4, characterized in that, In step (3), the mass ratio of the nano-dispersion, dispersant and water is 1:0.02-0.1:3-5.

7. The electron beam curable coating according to claim 4, characterized in that, In step (5), the initiator includes at least one of benzoyl peroxide, azobisisobutyronitrile, azobisisoheptanenitrile, persulfate, and azobisisobutylamidine dihydrochloride. The initiator accounts for 1-5% of the mass fraction of the oil phase, and the particle size of the electron beam cured coloring particles is 100-500 nm.

8. The electron beam curable coating according to claim 1, characterized in that, The crosslinking agent includes one or more of hydroxyethyl acrylate, trimethylolpropane triacrylate, hydroxyethyl methacrylate, N-hydroxymethylacrylamide, N,N-dimethylacrylamide, acrylic acid, and dodecyl methacrylate; the thickener includes one or more of sodium alginate, xanthan gum, starch derivatives, carboxymethyl cellulose, methyl cellulose, and polyacrylic acid polymers; and the cationic dye includes one or more of cationic yellow X-8GL, cationic golden yellow X-GL, cationic red GTL, cationic brilliant blue RL, cationic turquoise blue GB, cationic black WHL, and cationic blue M-RL.

9. The application of the electron beam curable coating according to any one of claims 1 to 8 in textile coloring, wherein the application involves applying the electron beam curable coating to the textile by padding, printing or spraying, and then subjecting it to electron beam curing, wherein the radiation dose of the electron beam curing is 10 kGy-80 kGy and the curing time is 0.1-3 s.

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