一种聚吡咯衍生多孔碳材料的制备方法和应用

By preparing polypyrrole-derived porous carbon materials to modify zinc anodes, the problems of dendrite growth and corrosion in aqueous zinc-ion batteries were solved, improving the cycle life and stability of the batteries and achieving high-efficiency zinc-ion battery performance.

CN119349544BActive Publication Date: 2026-07-17HARBIN INST OF TECH +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
HARBIN INST OF TECH
Filing Date
2024-10-14
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In practical applications, aqueous zinc-ion batteries face problems such as dendrite growth, corrosion, and hydrogen evolution, which can lead to short circuits and shortened battery life.

Method used

Polypyrrole-derived porous carbon material was used as a modifier for the zinc anode. The porous carbon material enriched with pyridine nitrogen and defects was prepared by etching with potassium permanganate to form a local environment that promotes the preferential deposition of zinc ions and reduces hydrogen evolution reaction and corrosion.

Benefits of technology

The dendrite problem of zinc anode was improved, enhancing the cycle life and stability of zinc-ion battery. The assembled Zn//Zn symmetric battery can cycle stably for more than 2000 hours at a current density of 2mA/cm2.

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Abstract

一种聚吡咯衍生多孔碳材料的制备方法和应用,它涉及一种多孔碳材料的制备方法和应用。本发明的目的是要解决目前水系锌离子电池在实际应用中面临的枝晶生长、腐蚀和析氢,进而造成电池短路、寿命缩短的问题。本发明以吡咯作为前驱体,通过高锰酸钾刻蚀制备多孔碳材料;该多孔碳材料具有富集的吡啶氮和大量缺陷的氮掺杂结构;通过控制蚀刻时间,可以精确调节氮掺杂类型和缺陷含量;其中,掺杂的氮元素中包含具有亲锌特性的吡啶氮和吡咯氮结构,能够有效富集锌离子。本发明制备的表面具有多孔碳涂层的锌负极具有循环寿命长和稳定性好的优势,且涂覆制备工艺简单,具有产业化前景。
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