一种序构超薄Cs0.33WO3纳米片及其制备方法和应用

By preparing ordered ultrathin Cs0.33WO3 nanosheets, the problems of poor thermodynamic stability and rapid recombination of photogenerated electrons and holes in the photocatalytic CO2 conversion reaction were solved, and efficient photocatalytic CO2 conversion under full-spectrum light, visible light and near-infrared light was realized.

CN119349641BActive Publication Date: 2026-07-17WUHAN UNIV OF TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
WUHAN UNIV OF TECH
Filing Date
2024-10-14
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing photocatalysts suffer from poor thermodynamic stability and low quantum efficiency in photocatalytic CO2 conversion reactions. They cannot effectively utilize near-infrared light, and the rapid recombination of photogenerated electrons and holes leads to low conversion efficiency and poor selectivity of the target product.

Method used

A method for preparing ordered ultrathin Cs0.33WO3 nanosheets was adopted. Using WO3·0.33H2O nanosheets and CsOH·H2O as raw materials, ordered ultrathin Cs0.33WO3 nanosheets with excellent photocatalytic performance were prepared by high-temperature calcination and used for photocatalytic CO2 conversion.

Benefits of technology

Under full-spectrum, visible, and near-infrared light irradiation, ordered ultrathin Cs0.33WO3 nanosheets exhibit excellent photocatalytic CO2 conversion performance, providing a large number of active sites and optimizing the electronic structure, thereby improving the separation and transfer efficiency of photogenerated carriers.

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Abstract

本发明涉及一种序构超薄Cs0.33WO3纳米片的制备方法,包括如下步骤:将Na2WO4·4H2O分散于去离子水中,溶解后,加入浓硝酸,搅拌、离心、洗涤、干燥后得到WO3·0.33H2O纳米片前驱体;将WO3·0.33H2O纳米片前驱体分散到去离子水溶液中,加入CsOH·H2O,搅拌,将得到的混合溶液盛装后,通入还原气体,放在第一温度环境中,升温到第二温度,还原一段时间后,洗涤、干燥得到序构超薄Cs0.33WO3纳米片。本发明的有益效果是:本发明制备的序构Cs0.33WO3光催化剂不仅提供了大量的活性位点,而且优化了电子结构,从而提高了活性位点的本征活性。此外,序构Cs0.33WO3有利于光生载流子的分离和转移。本发明制备的序构Cs0.33WO3在全谱光、可见光和近红外光照射下表现出优异的光催化CO2转化性能。
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