一种硼化钽钛 / MXenes双金属硼化物异质结材料及其制备方法和应用

By preparing tantalum titanium boride/MXenes bimetallic boride heterojunction materials through a stepwise calcination method, the problems of poor conductivity and lithium polysulfide shuttle effect in lithium-sulfur batteries were solved, achieving efficient material immobilization and improved electrochemical performance.

CN119390082BActive Publication Date: 2026-07-17GUANGDONG UNIV OF TECH

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
GUANGDONG UNIV OF TECH
Filing Date
2024-09-08
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In existing lithium-sulfur batteries, the active materials sulfur and lithium sulfide have poor conductivity and exhibit significant volume expansion during charge-discharge cycles. The shuttle effect of lithium polysulfides has not been effectively resolved, resulting in limited battery performance.

Method used

A stepwise calcination method was used to prepare tantalum titanium boride/MXenes bimetallic boride heterojunction materials. By using MXenes as a conductive substrate and combining the synergistic effect of different metals, elemental sulfur was fixed, the generation of lithium polysulfides was suppressed, and the conductivity and catalytic performance of the electrode materials were improved.

Benefits of technology

It effectively suppressed the shuttle effect in lithium-sulfur batteries, improved the conductivity and catalytic performance of electrode materials, enhanced electrochemical performance, reduced reaction temperature, and simplified the preparation process.

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Abstract

本发明属于纳米材料技术领域,公开了一种硼化钽钛 / MXenes双金属硼化物异质结材料及其制备方法和应用。将商业硼粉、五氧化二钽、二氧化钛、MXenes、氯化钠和氯化钾混合研磨,通过分步煅烧法在950‑1050℃氩气氛围下获得该材料。之后通过真空熔融扩散反应制备得到硫 / 硼化钽钛 / MXenes双金属异质结。本发明可控性好,得益于双金属硼化物独特的电子结构,丰富的活性位点,催化金属之间的协同效应,双亲硫性质使其能够固定更多的硫单质。本发明能够解决现有的锂硫电池中硫单质固定性较差的问题,抑制多硫化物溶解,提升储能能力,充分释放硼化物其活性位点,从而解决、抑制穿梭效应问题以及硼化物复合材料容易团聚的问题。
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