低热膨胀低摩擦聚酰亚胺复合材料、其制备方法及应用

By introducing phenylacetylene phthalic anhydride-modified γ-aminopropyltriethoxysilane-modified graphene oxide and chopped carbon fibers into polyimide materials, the wear resistance and dispersion problems of polyimide materials are solved, realizing a high-performance composite material with low friction and low thermal expansion, suitable for components such as engine bushings.

CN119391184BActive Publication Date: 2026-07-17AVIC BEIJING INST OF AERONAUTICAL MATERIALS

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
AVIC BEIJING INST OF AERONAUTICAL MATERIALS
Filing Date
2024-10-31
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polyimide materials have shortcomings in terms of wear resistance and dispersibility, resulting in significant energy loss and wear during equipment operation. Furthermore, common nanofillers have poor dispersibility in polyimide, limiting performance improvement.

Method used

Phenylacetylene phthalic anhydride-modified γ-aminopropyltriethoxysilane-modified graphene oxide and chopped carbon fibers were mixed with phenylacetylene-terminated polyimide resin to improve their compatibility and dispersion uniformity in the resin, thereby enhancing their abrasion resistance and thermal dimensional stability.

Benefits of technology

It significantly reduces the coefficient of friction and the coefficient of thermal expansion, and improves mechanical properties. The coefficient of friction is as low as 0.2, the tensile strength reaches 85.9MPa, and the modulus reaches 8.8GPa, making it suitable for wear-resistant parts such as engine bushings.

✦ Generated by Eureka AI based on patent content.

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Abstract

本发明公开了一种低热膨胀低摩擦聚酰亚胺复合材料、其制备方法及应用。本申请提供的低热膨胀低摩擦聚酰亚胺复合材料包括:苯乙炔封端聚酰亚胺树脂;苯乙炔苯酐改性γ‑氨丙基三乙氧基硅烷改性的氧化石墨烯;短切碳纤维。本申请采用苯乙炔苯酐改性γ‑氨丙基三乙氧基硅烷改性的氧化石墨烯和短切碳纤维共同对苯乙炔封端聚酰亚胺树脂进行增强,苯乙炔苯酐改性γ‑氨丙基三乙氧基硅烷改性的氧化石墨烯能够与苯乙炔封端聚酰亚胺树脂中发生反应,提高其在树脂中的相容性和分散均匀性,从而使得石墨烯和短切碳纤维发挥更好的协同作用,大幅提高苯乙炔封端聚酰亚胺树脂的耐摩擦性能、热尺寸稳定性和力学性能。
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