High-strength bio-based epoxy resin capable of being recycled in closed loop mode and preparation method, recycling method and application of high-strength bio-based epoxy resin

By using renewable bio-based epoxy compounds and amine-based compounds to prepare high-strength bio-based epoxy resins with ester bonds and tertiary amine autocatalytic functions, the toxicity and unsustainability of traditional epoxy resins are solved, and efficient recycling and sustainable development of materials are achieved.

CN119529237AActive Publication Date: 2025-02-28BEIJING FORESTRY UNIVERSITY
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Patent Information

Application Number
CN202411871162.2
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2024-12-18
Publication Date
2025-02-28
Estimated Expiration
2044-12-18

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Abstract

The invention discloses high-strength bio-based epoxy resin capable of being recycled in a closed-loop mode and a preparation method, a recycling method and application of the high-strength bio-based epoxy resin capable of being recycled in the closed-loop mode. The preparation method comprises the steps that 1, a lignin acid alcohol compound, epoxy chloropropane and a catalyst are subjected to a ring-opening reaction, then alkali metal hydroxide is added for a cyclization reaction, and a compound A is obtained; a lignin acid alcohol epoxy compound is prepared; and 2, carrying out a curing reaction on the lignin acid alcohol epoxy compound obtained in the step 1 and an amino compound to obtain the high-strength bio-based epoxy resin capable of being subjected to closed-loop recovery. The epoxy resin material prepared by the invention is a novel green, degradable and reusable high polymer material, and can be applied to the fields of fiber modification, coatings, adhesives and the like.
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