一种动力电池PACK用宽温域耐热双组分聚氨酯导热结构胶及其制备方法和应用

By introducing a ternary esterification structure of high EO modified polyol, PO polyether and bio-based polyol, combined with specific fillers and isocyanate prepolymer, a microphase structure with strong molecular binding force is formed, which solves the problem of balancing room temperature flexibility and high temperature heat resistance of structural adhesives for power battery PACK, and achieves high-performance bonding in a wide temperature range.

CN119529747BActive Publication Date: 2026-07-17WANHUA CHEM BEIJING

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
WANHUA CHEM BEIJING
Filing Date
2024-12-06
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing structural adhesives for power battery packs cannot simultaneously achieve both normal flexibility and high-temperature heat resistance. They cannot maintain excellent bonding strength and toughness in a wide temperature range environment, and there is a risk of high-temperature modulus loss and aging failure.

Method used

The ternary esterification structure of high EO modified polyol, PO polyether and bio-based polyol is adopted, combined with metal and non-metal inorganic fillers, and isocyanate-based polyurethane prepolymer to form a microphase structure with strong molecular binding force, which improves the stability of molecular chain segments at high temperature, and enhances the adhesion to metal surface through polyfunctional alkoxysilane.

Benefits of technology

It achieves a combination of low modulus and heat resistance of polyurethane adhesive in a wide temperature range environment, with high toughness and good bonding strength at room temperature, and stable modulus at high temperature. This reduces the risk of damage to power battery packs under long-term vibration and high-temperature conditions, and has excellent resistance to damp heat and thermal shock.

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Abstract

本发明提供一种动力电池PACK用宽温域耐热双组分聚氨酯导热结构胶及其制备方法和应用,所述双组分聚氨酯导热结构胶包括A组分和B组分,A组分包含以下组分:生物基多元醇、多元醇树脂A、多元醇树脂B、导热填料、触变剂、除水剂A、催化剂;B组分包含以下组分:异氰酸酯封端聚氨酯预聚体、导热填料、触变剂、除水剂B、偶联剂。本发明的聚氨酯导热结构胶,大幅提升耐湿热老化和耐高低温性能,实现了柔韧性与耐热性、耐老化的结合,具备宽温域适用性,适合应用于动力电池PACK热管理及结构粘结。
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